//A Textbook of Chemical Engineering Thermodynamics //Chapter 6 //Thermodynamic Properties of Pure Fluids //Example 1 clear; clc; //Given: betta = 1.25*10^-3; //coeffecient of expansion (K^-1) V = 0.1; //molar volume of organic liquid (m^3/kmol) P2 = 20; //final pressure (bar) P1 = 1; //initial pressure (bar) //To determine the change in entropy of system //betta = (1/V)*(del V/del T)p //Let k = (del V/del T)p k = betta*V; //Considering Maxwell's relation Eq. 6.24 (Page no. 193) //dS = -k*(dP) S = -k*(P2-P1)*10^5; //entropy change (J/kmol K) mprintf('Change in entropy is %f J/kmol K',S); mprintf('\n It is assumed that (del V/del T)p is constant in the pressure range 1 to 20 bar'); //end