clear; clc; // Illustration2.3 // Page: 32 printf('Illustration 2.3 - Page: 32\n\n'); // solution //***Data***// // a = C2H5OH b = air Pt = 101.3*10^(3);//[N/square m] T = 273;//[K] //********// Ma = 46.07;// [kg/kmol] Mb = 29;// [kg/kmol] //For air from Table 2.2 (Pg 33) Eb_by_k = 78.6;// [K] rb = 0.3711; // [nm] // For C2H5OH using Eqn. 2.38 & 2.39 // From Table 2.3 Va = (2*0.0148)+(6*0.0037)+(0.0074);// [cubic m/kmol] Tba = 351.4;// [K] ra = 1.18*(Va^(1/3));//[nm] Ea_by_k = 1.21*Tba;// [K] rab = (ra+rb)/2;// [nm] Eab_by_k = sqrt(Ea_by_k*Eb_by_k);// [K] Collision_value = T/Eab_by_k; //From Fig. 2.5 (Page: 32) f(collision value) Collision_func = 0.595; Dab = (10^(-4)*(1.084-(0.249*sqrt((1/Ma)+(1/Mb))))*T^(3/2)*sqrt((1/Ma)+(1/Mb)))/(Pt*(rab^2)*Collision_func);//[square m/s] printf('The diffusivity of ethanol through air at 1 atm. & 0C is %e square m/s\n',Dab); printf('The observed value (Table 2.1) is 1.02*10^(-5) square m/s')