// Estimate the Enthaply of Combustion for Methane //Exaample 4.11 clc; clear; H1=414; //Bond Enthalpy for a C-H bond in kJ mol^-1 H2=498.8; //Bond Enthalpy for a O-O bond in kJ mol^-1 H3=799; //Bond Enthalpy for a C=O bond kJ mol^-1 H4=460; //Bond Enthalpy for a O-H bond kJ mol^-1 delHr=((4*H1)+(2*H2))-((2*H3)+(4*H4)); //Enthalpy of the reaction kJ mol^-1 printf("Enthalpy Change of combustion of methane = %.1f kJ mol^-1",delHr); H5=-393.5; //Enthalpy of formation of CO2 kJ mol^-1 H6=-241.8; //Enthalpy of formation of H2O kJ mol^-1 H7=-74.85; //Enthalpy of formation of CH4 kJ mol^-1 delHf=(H5+(2*H6))-H7; //Enthalpy of formation kJ mol^-1 printf("\nEnthalpy Change of combustion of methane from enthalpy of formation = %.1f kJ mol^-1",delHf);