//// //Varialble Declaration Tn = 353.24 //normal boiling point of Benzene, K pi = 1.19e4 //Vapor pressure of benzene at 20°C, Pa DHf = 9.95 //Latent heat of fusion, kJ/mol pv443 = 137. //Vapor pressure of benzene at -44.3°C, Pa R = 8.314 //Ideal Gas Constant, J/(mol.K) Pf = 101325 //Std. atmospheric pressure, Pa T20 = 293.15 //Temperature in K P0 = 1. Pl = 10000. Ts = -44.3 //Temperature of solid benzene, °C //Calculations Ts = Ts + 273.15 //Part a DHv = -(R*log(Pf/pi))/(1./Tn-1./T20) //Part b DSv = DHv/Tn DHf = DHf*1e3 //Part c Ttp = -DHf/(R*(log(Pl/P0)-log(pv443/P0)-(DHv+DHf)/(R*Ts)+DHv/(R*T20))) Ptp = exp(-DHv/R*(1./Ttp-1./Tn))*101325 //Results printf("\n Latent heat of vaporization of benzene at 20°C %4.1f kJ/mol",DHv/1000) printf("\n Entropy Change of vaporization of benzene at 20°C %3.1f J/mol",DSv) printf("\n Triple point temperature = %4.1f K for benzene",Ttp) printf("\n Triple point pressure = %4.2e Pa for benzene",Ptp)