//// //Variable Declaration n = 3.0 //Number of moles of CO2 Ti = 300 //Initial and final state Temeperatures of CO2, K Tf = 600 pi = 1.00 //Initial and final state pressure of CO2, K pf = 3.00 cpm = 27.98 //Specific heat of mercury, J/(mol.K) M = 200.59 //Molecualr wt of mercury, g/(mol) beta = 1.81e-4 //per K rho = 13.54 //Density of mercury, g/cm3 R = 8.314 //Ideal Gas Constant, J/(mol.K) //Calcualtions dS1 = n*cpm*log(Tf/Ti) dS2 = n*(M/(rho*1e6))*beta*(pf-pi)*1e5 dS = dS1 - dS2 //Results printf("\n Entropy change of process is %4.1f J/(mol.K)",dS) printf("\n Ratio of pressure to temperature dependent term %3.1e\nhence effect of pressure dependent term is very less",dS2/dS1) printf("\n The above value is different as given in the text")