//// //Variable Declaration R = 8.314 //Ideal Gas Constant, J/(mol.K) T = 298 //Temperature of Gas, K MAr = 0.04 //Molecular wt of Ar, kg/mol MKr = 0.084 //Molecular wt of Kr, kg/mol pAr = 360 //Partial Pressure Ar, torr pKr = 400 //Partial Pressure Kr, torr rAr = 0.17e-9 //Hard sphere radius of Ar, m rKr = 0.20e-9 //Hard sphere radius of Kr, m NA = 6.022e23 //Number of particles per mol k = 1.38e-23 //Boltzmann constant, J/K //Calculations pAr = pAr*101325/760 pKr = pKr*101325/760 p1 = pAr*NA/(R*T) p2 = pKr*NA/(R*T) sigm = %pi*(rAr+rKr)**2 mu = MAr*MKr/((MAr+MKr)*NA) p3 = sqrt(8*k*T/(%pi*mu)) zArKr = p1*p2*sigm*p3 //Results printf("\n Collisional frequency is %4.2e m-3s-1",zArKr)