clear clc M1=76;//molar mass of CS2 in gm w2=3.795;//weight of S in 100gm of CS2 in gm w1=100;//weight of CS2 R=8.314;//in J/Kmol Tb=319.81;//boiling point of CS2 in K Tbp=319.45;//boiling point of pure CS2 in K DelHm_v=351.87;//enthalpy of vaporization in J/gm M2=(w2*M1*R*(Tb^2))/(w1*(Tb-Tbp)*DelHm_v*76) printf('M2=%.1f gm/mol',M2) N=M2/32;//no. of s atoms printf('\nN=%.1f',N) //Molecular formula S8 //There are some errors in the solution given in textbook //page 53