//Chapter-5,Example 2,Page 122 clc(); close(); t=[7.18 18 27.05] //time in minute r=[ 21.4 17.7 15] //rotation in degrees r_0=24.09 r_a=-10.74 k=(1 ./t).*log10((r_0-r_a)./(r-r_a)) printf('values of k') disp(k) printf('since k values are fairly constant by putting in 1nd order rate equation. \nHence hydrolysis of methyl acetate is of 1st order.')