//Example 7.27 clear; clc; //Given R=0.082;//gas constant in atm dm^3 K^-1 mol^-1 m=0.1;//molality of acid solution in mol kg^-1 T=298;//temperature in K w1=1000;//mass of water in g //To determine the partial molar volume and the density V2=16.62+(1.5*1.77*sqrt(m))+(2*0.12*m);//partial molar volume in cm^3 mol^-1 V=1003+(16.62*m)+(1.77*m^(3/2))+(0.12*m^2);//total volume in cm^3 V1=(V-(m*V2))/55.55;//partial molar volume of water in cm^3 mol^-1 p1=(w1+5.85)/V;//density of te solution in g cm^-3 mprintf('The partial molar volume of water = %f cm^3 mol^-1',V1); mprintf('\n The partial molar volume of sodium chloride = %f cm^3 mol^-1',V2); mprintf('\n The density = %f g cm^-3',p1); //end