//Example 6.5 clear; clc; //Given T1=323;//temperature in K T2=322;//temperature in K T21=324;//temperature in K n=2;//moles of water NA=6.023*(10^23);//avogadros number Cp=75;//specific heat at constant pressure of water in J K^-1 mol^-1 k=1.38*(10^(-23));//in J K^-1 //To calculate the probability delS=Cp*log(T2*T21/T1^2);//entropy change in J mol^-1 K^-1 p=exp(delS/k);//probability mprintf('Probability that 2 moles of water at 323 K will break down into two drops at 322 and 324 K each 1 mole is negligibly small = %f',p); //end