//Example 3.2 clear; clc; //Given delH1 = -393.5//H1 is the heat of reaction in the formation of CARBON DIOXIDE in kJ (i) delH2 = -110.5//H2 is the heat of reaction in the formation of CARBON MONOXIDE in kJ (ii) delH3 = -890.35//H3 is the heat of reaction in the combustion of METHANE in kJ (iii) delH4 = -85.3//H4 is the heat of reaction in the formation of SILVER CHLORIDE in kJ (iv) R = 0.008314;//R is gas constant in kJ K^-1 mol^-1 T = 298;//T is temperature in K //To determine the heat of formation delv1= 1-(1);//change in moles in reaction (i) delE1 = delH1 - (delv1*R*T);//E1 is the internal energy (i) in kJ (1st law of thermodynamics) mprintf('(i) change in internal energy = %f kJ',delE1); delv2=1-(0.5);//change in moles in reaction (ii) delE2 = delH2 - (delv2*R*T);//E2 is the internal energy (ii) in kJ (1st law of thermodynamics) mprintf('\n (ii) change in internal energy = %f kJ',delE2); delv3=1-(1+2);//change in moles in reaction (iii) delE3 = delH3 - (delv3*R*T);//E3 is the internal energy (iii) in kJ (1st law of thermodynamics) mprintf('\n (iii) change in internal energy = %f kJ',delE3); delv4=0-(1);//change in moles in reaction (iv) delE4 = delH4 - (delv4*R*T);//E4 is the internal energy (iv) in kJ (1st law of thermodynamics) mprintf('\n (iv) change in internal energy = %f kJ',delE4); //end