//Example 3.14 clear; clc; //Given delHsubLi = 161;//heat of sublimation of Li in kJ delHsubNa = 109;//heat of sublimation of Na in kJ delHd = 122;//heat of dissociation of chlorine in kJ delHaff = -350;//electron affinity of Cl in kJ delHipLi = 520;// ionization potential of Li in kJ delHipNa = 496;//ioization potential of Na in kJ delHfLiCl = -410;//heat of formation of LiCl in kJ delHfNaCl = -411;//heat of formation of NaCl in kJ delHLisol= -35.1;//heat of solution of LiCl in kJ delHNasol= 4.3;//heat of solution of NaCl in kJ //To determine the (a) enthalpy change (b) heat of hydration delHcLiCl = delHsubLi+delHd+delHipLi+delHaff-delHfLiCl;//born haber cycle mprintf('(a) heat of formation of LiCl crystal = %f kJ',delHcLiCl); delHcNaCl = delHsubNa+delHd+delHipNa+delHaff-delHfNaCl;//born haber cycle mprintf('\n heat of formation of NaCl crystal = %f kJ',delHcNaCl); delHLiCl = delHLisol-delHcLiCl;//heat of hydration of LiCl in kJ delHNaCl = delHNasol-delHcNaCl;//heat of hydration of NaCl in kJ mprintf('\n \n (b) heat of hydration of LiCl = %f kJ',delHLiCl); mprintf('\n heat of hydration of NaCl = %f kJ',delHNaCl); //end