//Example 2.9 clear; clc; //Given R=8.314;// gas constant in J K^-1 mol^-1 t1=298;// temperature in K p1=303975;// initial pressure in Pa v1=1.43;//initial volume in dm^3 v2=2.86;// final volume in dm^3 Cp=29.1;// heat capacity at constant pressure in J mol^-1 K^-1 // To determine t2,p2,w,delH and DelE Cv=Cp-R;//heat capacity at constant volume t2=t1*((v1/v2)^(R/Cv));//final temperature in K p2=p1*((v1/v2)^(Cp/Cv));//final pressure in Pa n=(p1*v1*0.001)/(R*t1);//number of moles delE=n*Cv*(t2-t1);//delE in J w=delE;//work done in J delH=n*Cp*(t2-t1);//enthalpy change in J mprintf('Final Temperature = %f K',t2); mprintf('\n Final Pressure = %f Pa',p2); mprintf('\n delE = %f J',delE); mprintf('\n delH = %f J',delH); mprintf('\n w = %f J',w); //end