//Example 2.11 clear; clc; //Given R=8.314;// gas constant in J K^-1 mol^-1 t1=300;// temperature in K p1=1000;// initial pressure in Mpa p2=100;// final pressure in Mpa Cv=1.5*R;// heat capacity at constant volume in J K^-1 mol^-1 W=0.1;// weight of CO taken in kg n=1;//moles of the gas // To determine q,w,delH and delE Cp=Cv+R;//heat capacity at constant pressure //(a) isothermal reversible w=(-1)*R*t1*log(p1/p2);//work done in J q=(-1)*w;//heat in J //(b) isothermal irreversible w1=(-1)*R*t1*(1-(p2/p1));//work done in J q1=(-1)*w1;//heat in J //(c) adiabatic reversible t2=t1*((p2/p1)^(R/Cp)); delE=n*Cv*(t2-t1);//change in internal energy in J delH=n*Cp*(t2-t1);//change in enthalpy in J //(d) adiabatic irreversible T2=t1*((Cv+((p2/p1)*R))/Cp);//final temperature in K delE1=n*Cv*(T2-t1);//change in internal energy in J delH1=n*Cp*(T2-t1);//change in enthalpy in J mprintf('(a) w = %f J mol^-1,delH = 0 J mol^-1,q= %f J mol^-1 and delE = 0 J mol^-1',w,q); mprintf('\n (b) w = %f J mol^-1,delH = 0 J mol^-1,q= %f J mol^-1 and delE = 0 J mol^-1',w1,q1); mprintf('\n (c) T2 = %f K,w = %f J mol^-1,delH = %f J mol^-1,q= 0 J mol^-1 and delE = %f J mol^-1',t2,delE,delH,delE); mprintf('\n (d) T2 = %f K,w = %f J mol^-1,delH = %f J mol^-1,q= 0 J mol^-1 and delE = %f J mol^-1',T2,delE1,delH1,delE1); //end