From b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b Mon Sep 17 00:00:00 2001 From: priyanka Date: Wed, 24 Jun 2015 15:03:17 +0530 Subject: initial commit / add all books --- 611/CH13/EX13.1/Chap13_Ex1.sce | 27 +++++++++++++++++++++++++++ 611/CH13/EX13.2/Chap13_Ex2_R1.sce | 28 ++++++++++++++++++++++++++++ 611/CH13/EX13.3/Chap13_Ex3_R1.sce | 24 ++++++++++++++++++++++++ 611/CH13/EX13.4/Chap13_Ex4.sce | 23 +++++++++++++++++++++++ 611/CH13/EX13.5/Chap13_Ex5.sce | 21 +++++++++++++++++++++ 5 files changed, 123 insertions(+) create mode 100755 611/CH13/EX13.1/Chap13_Ex1.sce create mode 100755 611/CH13/EX13.2/Chap13_Ex2_R1.sce create mode 100755 611/CH13/EX13.3/Chap13_Ex3_R1.sce create mode 100755 611/CH13/EX13.4/Chap13_Ex4.sce create mode 100755 611/CH13/EX13.5/Chap13_Ex5.sce (limited to '611/CH13') diff --git a/611/CH13/EX13.1/Chap13_Ex1.sce b/611/CH13/EX13.1/Chap13_Ex1.sce new file mode 100755 index 000000000..66b2bece0 --- /dev/null +++ b/611/CH13/EX13.1/Chap13_Ex1.sce @@ -0,0 +1,27 @@ +// Y.V.C.Rao ,1997.Chemical Engineering Thermodynamics.Universities Press,Hyderabad,India. + +//Chapter-13,Example 1,Page 478 +//Title:Depression in freezing point +//================================================================================================================ +clear +clc + +//INPUT +weight=10; //weight of NaCl in grams +volume=1; //volume of water in litres +weight_water=1000; // weight of water in grams (Weight=Volume*Density, density of water =1g/cc=1g/ml=1000g/l) +molwt_NaCl=58.5; //molecular weight of NaCl in grams +molwt_water=18; //molecular weight of water in grams +hf=6.002; //enthalpy change of fusion in kJ/mol at 0 degree celsius +P=101.325; //pressure in kPa +T=273.15; // freezing point temperature of water at the given pressure in K +R=8.314; //universal gas constant in J/molK; + +//CALCULATION +x2=(weight/molwt_NaCl)/((weight/molwt_NaCl)+(weight_water/molwt_water));// calculation of mole fraction of solute NaCl (no unit) +delt=(R*T^2*x2)/(hf*10^3);//calculation of depression in freezing point of water using Eq.(13.14) + +//OUTPUT +mprintf('\n The depression in freezing point of water when 10g of NaCl solute is added = %0.2f K',delt); + +//===============================================END OF PROGRAM=================================================== diff --git a/611/CH13/EX13.2/Chap13_Ex2_R1.sce b/611/CH13/EX13.2/Chap13_Ex2_R1.sce new file mode 100755 index 000000000..9f7787158 --- /dev/null +++ b/611/CH13/EX13.2/Chap13_Ex2_R1.sce @@ -0,0 +1,28 @@ +// Y.V.C.Rao ,1997.Chemical Engineering Thermodynamics.Universities Press,Hyderabad,India. + +//Chapter-13,Example 2,Page 480 +//Title:Elevation in Boiling Point +//================================================================================================================ +clear +clc + +//INPUT +weight=10; //weight of NaCl in grams +volume=1; //volume of water in litres +weight_water=1000; // weight of water in grams (Weight=Volume*Density, density of water =1g/cc=1g/ml=1000g/l) +molwt_NaCl=58.5; //molecular weight of NaCl in grams +molwt_water=18; //molecular weight of water in grams +lat_ht=2256.94; //latent heat of vaporization in kJ/kg at 100 degree celsius (obtained from steam tables) +P=101.325; //pressure in kPa +T=373.15; //boiling point temperature of water at the given pressure in K +R=8.314; //universal gas constant in J/molK + +//CALCULATION +x2=0.0031;//mole fraction of solute NaCl (From Example 13.1)(no unit) +hv=(lat_ht*molwt_water)/1000; //conversion of latent heat from kJ/kg to kJ/mol +delt=(R*T^2*x2)/(hv*10^3); //calculation of elevation in boiling point of water using Eq.(13.24) + +//OUTPUT +mprintf('\n The elevation in boiling point of water when 10g of NaCl solute is added = %0.2f K',delt); + +//===============================================END OF PROGRAM=================================================== diff --git a/611/CH13/EX13.3/Chap13_Ex3_R1.sce b/611/CH13/EX13.3/Chap13_Ex3_R1.sce new file mode 100755 index 000000000..325b8783d --- /dev/null +++ b/611/CH13/EX13.3/Chap13_Ex3_R1.sce @@ -0,0 +1,24 @@ +// Y.V.C.Rao ,1997.Chemical Engineering Thermodynamics.Universities Press,Hyderabad,India. + +//Chapter-13,Example 3,Page 481 +//Title:Osmotic pressure +//================================================================================================================ +clear +clc + +//INPUT +weight=10; //weight of NaCl in grams +weight_water=1000; // weight of water in grams +molwt_NaCl=58.5; //molecular weight of NaCl in grams +molwt_water=18; //molecular weight of water in grams +T=300; //prevailing temperature of water in K +R=8.314; //universal gas constant in (Pa m^3)/(mol K); +v=18*10^-6;//molar volume in m^3/mol +//CALCULATION +x2=0.0031;//mole fraction of solute NaCl (From Example 13.1)(no unit) +pi=((R*T*x2)/v)*10^-3; // calulation of osmotic pressure using Eq(13.30)(in kPa) + +//OUTPUT +mprintf('\n The osmotic pressure of a solution conatining 10g of NaCl in 1000g of water at 300K = %0.2f kPa',pi); + +//===============================================END OF PROGRAM=================================================== diff --git a/611/CH13/EX13.4/Chap13_Ex4.sce b/611/CH13/EX13.4/Chap13_Ex4.sce new file mode 100755 index 000000000..922270d48 --- /dev/null +++ b/611/CH13/EX13.4/Chap13_Ex4.sce @@ -0,0 +1,23 @@ +// Y.V.C.Rao ,1997.Chemical Engineering Thermodynamics.Universities Press,Hyderabad,India. + +//Chapter-13,Example 4,Page 483 +//Title:Ideal solubility +//================================================================================================================ +clear +clc + +//INPUT +temp=20; // prevailing tempearture in degree celsius +melt_temp=80.05; // melting point of naphthalene in degree celsius +hf=18.574; // enthalpy of fusion in kJ/mol +R=8.314; // universal gas constant in J/molK + +//CALCULATION +t=temp+273.15; // convesion of prevailing temperature to K +melt_t=melt_temp+273.15; //conversion of melting point of naphtalene to K +x2=exp(((hf*10^3)/R)*((1/melt_t)-(1/t))); //calculation of ideal solubility using Eq.(13.40)(no unit) + +//OUTPUT +mprintf('\n The ideal solubility of naphthalene at 20 degree celsius= %0.4f',x2); + +//===============================================END OF PROGRAM=================================================== diff --git a/611/CH13/EX13.5/Chap13_Ex5.sce b/611/CH13/EX13.5/Chap13_Ex5.sce new file mode 100755 index 000000000..c2f90edbd --- /dev/null +++ b/611/CH13/EX13.5/Chap13_Ex5.sce @@ -0,0 +1,21 @@ +// Y.V.C.Rao ,1997.Chemical Engineering Thermodynamics.Universities Press,Hyderabad,India. + +//Chapter-13,Example 5,Page 483 +//Title:Solubility of gas +//================================================================================================================ +clear +clc + +//INPUT +t=295.43; //prevailing temperature in K +sat_p=6.05; //Sasturation pressure of carbon dioxide at the prevailing temperature in MPa +p=0.1; //pressure at which solubility has to be determined in MPa + +//CALCULATION +x2=p/sat_p; //calculation of solubility using Eq.(13.44)(no unit) + +//OUTPUT +mprintf('\n The solubility of carbon dioxide expressed in mole fraction of carbon dioxide in solution at 0.1MPa= %0.4f',x2); + +//===============================================END OF PROGRAM=================================================== + -- cgit