From b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b Mon Sep 17 00:00:00 2001 From: priyanka Date: Wed, 24 Jun 2015 15:03:17 +0530 Subject: initial commit / add all books --- 572/CH14/EX14.4/c14_4.sce | 25 +++++++++++++++++++++++++ 1 file changed, 25 insertions(+) create mode 100755 572/CH14/EX14.4/c14_4.sce (limited to '572/CH14/EX14.4') diff --git a/572/CH14/EX14.4/c14_4.sce b/572/CH14/EX14.4/c14_4.sce new file mode 100755 index 000000000..74401fc65 --- /dev/null +++ b/572/CH14/EX14.4/c14_4.sce @@ -0,0 +1,25 @@ +//(14.4) One kilomole of carbon monoxide reacts with the theoretical amount of air to form an equilibrium mixture of CO2, CO, O2, and N2 at 2500 K and 1 atm. Determine the equilibrium composition in terms of mole fractions, and compare with the result of Example 14.2. + + + +//solution + +//For a complete reaction of CO with the theoretical amount of air +//CO + .5 O2 + 1.88N2 -----> CO2 + 1.88N2 +//Accordingly, the reaction of CO with the theoretical amount of air to form CO2, CO, O2, and N2 is +//CO + .5O2 + 1.88N2 ---> zCO + z/2 O2 + (1-z)CO2 + 1.88N2 + +K = .0363 //equilibrium constant the solution to Example 14.2 +p =1 //in atm +pref = 1 //in atm + +//solving K = (z*z^.5/(1-z))*((p/pref)*2/(5.76+z))^.5 gives +z = .175 +yCO = 2*z/(5.76 + z) +yO2 = z/(5.76 + z) +yCO2 = 2*(1-z)/(5.76 + z) +yN2 = 3.76/(5.76 + z) +printf('the mole fraction of CO is: %f',yCO) +printf('\nthe mole fraction of O2 is: %f',yO2) +printf('\nthe mole fraction of CO2 is: %f',yCO2) +printf('\nthe mole fraction of N2 is: %f',yN2) \ No newline at end of file -- cgit