From b1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b Mon Sep 17 00:00:00 2001 From: priyanka Date: Wed, 24 Jun 2015 15:03:17 +0530 Subject: initial commit / add all books --- 479/CH14/EX14.4/Example_14_4.sce | 47 ++++++++++++++++++++++++++++++++++++++++ 479/CH14/EX14.4/Example_14_4.txt | 3 +++ 2 files changed, 50 insertions(+) create mode 100755 479/CH14/EX14.4/Example_14_4.sce create mode 100755 479/CH14/EX14.4/Example_14_4.txt (limited to '479/CH14/EX14.4') diff --git a/479/CH14/EX14.4/Example_14_4.sce b/479/CH14/EX14.4/Example_14_4.sce new file mode 100755 index 000000000..883ee4d45 --- /dev/null +++ b/479/CH14/EX14.4/Example_14_4.sce @@ -0,0 +1,47 @@ +//Chemical Engineering Thermodynamics +//Chapter 14 +//Thermodynamics of Chemical Reactions + +//Example 14.4 +clear; +clc; + +//Given +//Basis: 1Kgmole of C0 +//CO + (1/2)O2 - CO2 +//Whem mixture entered,their compositions are given as: +n_CO = 1;//Kgmole +del_H = -67636;//Standard heat of reaction in Kcal/Kgmole at 25 deg cel +T1 = 95;//Temperature at which mixture entered in deg celsius +T2 = 25;//Intermediate temperature in deg celsius +//Mean specific heat values for the temperature between 25 and 95 deg celsius in Kcal/Kgmole are given as (from figure 14.4)(page no 303) +Cpm_CO = 6.95; +Cpm_O2 = 7.1; +Cpm_N2 = 6.95; + +//To Calculate the theoretical flame temperature when both air and CO2 enter at 95 deg celsius +n_O2 = 1;//Kgmole, as 100% excess air is given +n_N2 = n_O2*(0.79/0.21);//Kgmole +//After the rxn: +n_CO2 = n_CO;//Kgmole +n_O2_r = n_O2-(n_CO/2);//remaining Kgmole of O2 +//In equation 14.18 (page no 307) say: H_2-H_R = Ha, H_P-H_3 = Hb, Hc = del_H+Ha & Ht = Hc+Hb +Ha = (n_CO*Cpm_CO + n_O2*Cpm_O2 + n_N2*Cpm_N2)*(T2-T1);//in Kcal/Kgmole +Hc = del_H+Ha;//in Kcal/Kgmole +//For calculating Hb let us assume the temperature as +T = [530 1000 1650];//in deg celsius +Cpm_CO2 = [10.85 12 12.75];//Mean specific heat of CO2 at the coresspondig temperature (from figure 14.4) +Cpm_O2 = [7.55 7.8 8.3];//Mean specific heat of O2 at the coresspondig temperature (from figure 14.4) +Cpm_N2 = [7.15 7.5 7.85];//Mean specific heat of N2 at the coresspondig temperature (from figure 14.4) +for i = 1:3 + Hb(i) = (n_CO2*Cpm_CO2(i)+n_O2_r*Cpm_O2(i)+n_N2*Cpm_N2(i))*(T(i)-T2);//in Kcal/Kgmole + Ht(i) = Hc+Hb(i);//in Kcal/Kgmole +end +clf; +plot(T,Ht); +xtitle(" ","Temperature, deg celsius","Ht in Kcal/Kgmole"); +a = get("current_axes"); +set(a,"x_location","origin"); +Tf = interpln([Ht';T],0); +mprintf('The adiabatic temperature is read as %d degree celsius',Tf); +//end \ No newline at end of file diff --git a/479/CH14/EX14.4/Example_14_4.txt b/479/CH14/EX14.4/Example_14_4.txt new file mode 100755 index 000000000..c590523d9 --- /dev/null +++ b/479/CH14/EX14.4/Example_14_4.txt @@ -0,0 +1,3 @@ +For example 14.4,the answer given in the book is temperature as 1610 degree celsius. + But i am getting temperature as 1560 degree celsius. + There might be some calculation mistake in the book. \ No newline at end of file -- cgit