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authorpriyanka2015-06-24 15:03:17 +0530
committerpriyanka2015-06-24 15:03:17 +0530
commitb1f5c3f8d6671b4331cef1dcebdf63b7a43a3a2b (patch)
treeab291cffc65280e58ac82470ba63fbcca7805165 /2489/CH13
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Diffstat (limited to '2489/CH13')
-rwxr-xr-x2489/CH13/EX13.1/13_1.sce12
-rwxr-xr-x2489/CH13/EX13.2/13_2.sce21
-rwxr-xr-x2489/CH13/EX13.3/13_3.sce13
-rwxr-xr-x2489/CH13/EX13.4/13_4.sce17
-rwxr-xr-x2489/CH13/EX13.5/13_5.sce12
-rwxr-xr-x2489/CH13/EX13.6/13_6.sce9
-rwxr-xr-x2489/CH13/EX13.7/13_7.sce18
-rwxr-xr-x2489/CH13/EX13.8/13_8.sce19
-rwxr-xr-x2489/CH13/EX13.9/13_9.sce11
9 files changed, 132 insertions, 0 deletions
diff --git a/2489/CH13/EX13.1/13_1.sce b/2489/CH13/EX13.1/13_1.sce
new file mode 100755
index 000000000..2d4407d6e
--- /dev/null
+++ b/2489/CH13/EX13.1/13_1.sce
@@ -0,0 +1,12 @@
+clc
+//Intitalisation of variables
+clear
+F= 96500 //coulombs
+t= 3600 //sec
+n= 0.75 //mole
+v= 22.4 //lit
+v1= 0.336 //lit
+//CALCULATIONS
+cs= F*v1/(n*v*t)
+//RESULTS
+printf ('Current strength = %.3f amp',cs)
diff --git a/2489/CH13/EX13.2/13_2.sce b/2489/CH13/EX13.2/13_2.sce
new file mode 100755
index 000000000..70769d459
--- /dev/null
+++ b/2489/CH13/EX13.2/13_2.sce
@@ -0,0 +1,21 @@
+clc
+//Intitalisation of variables
+clear
+m= 1.9768 //gms
+M= 107.88 //gms
+m1= 5.136 ///gms
+M1= 74.56 //gms
+x1= 100 //gms
+x2= 3.65 //gms
+M2= 122.93 //gms
+//CALCULATIONS
+n1= m/M
+n2= m1/M1
+n3= (x2/M1)*(M2-m1)/(x1-x2)
+t= (n3-n2+n1)/n1
+t1= 1-t
+//RESULTS
+printf ('number of g equiv of Ag deposited = %.5f ',n1)
+printf ('\n number of g equiv of Ag deposited = %.5f ',n2)
+printf ('\n number of g equiv of KCl deposited = %.5f g equiv of KCl',n3)
+printf ('\n transference number = %.3f ',t1-0.003)
diff --git a/2489/CH13/EX13.3/13_3.sce b/2489/CH13/EX13.3/13_3.sce
new file mode 100755
index 000000000..41399c36e
--- /dev/null
+++ b/2489/CH13/EX13.3/13_3.sce
@@ -0,0 +1,13 @@
+clc
+//Intitalisation of variables
+clear
+l= 5.6 //cm
+F= 96500 //coloumbs
+A= 0.1142 //cm^2
+t= 2130 //sec
+i= 0.005893 //amp
+m= 10^-4 //gms
+//CALCULATIONS
+t= 1-(l*A*F*m/(i*t))
+//RESULTS
+printf ('Transference number = %.3f ',t)
diff --git a/2489/CH13/EX13.4/13_4.sce b/2489/CH13/EX13.4/13_4.sce
new file mode 100755
index 000000000..3111b9386
--- /dev/null
+++ b/2489/CH13/EX13.4/13_4.sce
@@ -0,0 +1,17 @@
+
+clc
+//Intitalisation of variables
+clear
+k= 0.012856 //ohm^-1 cm^-1
+R= 3468.9 //ohms
+k1= 44.597 //cm^-1
+c= 0.1 //g equiv per litre
+R1= 4573.6 //ohms
+//CALCULATIONS
+k1= k*R
+K= k1/R1
+a= 1000*K/c
+//RESULTS
+printf ('cell constant = %.3f cm^-1',k1)
+printf ('\n cell constant = %.5f ohm^-1 cm^-1',K)
+printf ('\n Equivalent conductance = %.2f ohms^-1 cm^2',a)
diff --git a/2489/CH13/EX13.5/13_5.sce b/2489/CH13/EX13.5/13_5.sce
new file mode 100755
index 000000000..0c4eeb392
--- /dev/null
+++ b/2489/CH13/EX13.5/13_5.sce
@@ -0,0 +1,12 @@
+clc
+//Intitalisation of variables
+clear
+A= 48.15 //ohm^-1 cm6-1
+m= 1.0283*10^-3 //gms equiv acid per litre
+A0= 390.7 //ohms^-1 cm^2
+A1= 60.2
+B= 0.229
+//CALCULATIONS
+a= A/(A0-(A1+B*A0)*sqrt((A/A0)*m))
+//RESULTS
+printf ('Degree of dissociation = %.4f',a)
diff --git a/2489/CH13/EX13.6/13_6.sce b/2489/CH13/EX13.6/13_6.sce
new file mode 100755
index 000000000..965ce4b6c
--- /dev/null
+++ b/2489/CH13/EX13.6/13_6.sce
@@ -0,0 +1,9 @@
+clc
+//Intitalisation of variables
+clear
+t= 0.3965
+A0= 126.45 //ohm^-1 CM62
+//CALCULATIONS
+l= (1-t)*A0
+//RESULTS
+printf ('ion conductance of the Cl- ion = %.2f ohms^-1 cm^2',l)
diff --git a/2489/CH13/EX13.7/13_7.sce b/2489/CH13/EX13.7/13_7.sce
new file mode 100755
index 000000000..6d6ad56a7
--- /dev/null
+++ b/2489/CH13/EX13.7/13_7.sce
@@ -0,0 +1,18 @@
+clc
+//Intitalisation of variables
+clear
+A1= 426.16 //ohms^-1 cm^2
+A2= 91 //ohms^-1 cm^2
+A3= 126.45 //ohms^-1 cm^2
+a1= 61.92 //ohms^-1 cm^2
+a2= 76.34 //ohms^-1 cm^2
+a3= 63.64 //ohms^-1 cm^2
+a4= 79.8 //ohms^-1 cm^2
+//CALCULATIONS
+A4= A1+A2-A3
+A5= a1+a2
+A6= a3+a4
+//RESULTS
+printf ('Conductance of CH3COOH = %.1f ohms^-1 cm^2',A4)
+printf ('\n Conductance of AgCl = %.1f ohms^-1 cm^2',A5)
+printf ('\n Conductance of BaSO4 = %.1f ohms^-1 cm^2',A6)
diff --git a/2489/CH13/EX13.8/13_8.sce b/2489/CH13/EX13.8/13_8.sce
new file mode 100755
index 000000000..f06473cf7
--- /dev/null
+++ b/2489/CH13/EX13.8/13_8.sce
@@ -0,0 +1,19 @@
+clc
+//Intitalisation of variables
+clear
+e= 5.6 //volts
+l= 9.8 //cm
+t= 1 //hr
+T= 25 //C
+A= 73.4 //ohm^-1 cm^2
+F= 96500 //coloumbs
+//CALCULATIONS
+v= A/F
+pg= e/l
+v1= v*pg
+L= v1*t*3600
+//RESULTS
+printf ('Mobility = %.2e cm/sec',v)
+printf ('\n Potential gradient = %.3f volt/cm',pg)
+printf ('\n Potential gradient = %.3f volt/cm',pg)
+printf ('\n Distance moved by ion = %.2f cm',L)
diff --git a/2489/CH13/EX13.9/13_9.sce b/2489/CH13/EX13.9/13_9.sce
new file mode 100755
index 000000000..52c856441
--- /dev/null
+++ b/2489/CH13/EX13.9/13_9.sce
@@ -0,0 +1,11 @@
+clc
+//Intitalisation of variables
+clear
+Ao= 138.3 //ohms^-1
+k1= 3.41*10^-6 //ohm^-1 cm^-1
+k2= 1.6*10^-6 //ohm^-1 cm^-1
+T= 25 //C
+//CALCULATIONS
+s= 1000*(k1-k2)/Ao
+//RESULTS
+printf ('Solubility of AgCl in water = %.2e g equiv per liter',s)