{ "metadata": { "name": "", "signature": "sha256:972acff7d45b02187de1954b7975da8c6079f6322a8b7b9b83d194bbf84a5e53" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 7 : The second law of thermodynamics" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 7.1 Page No : 137" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "T1 = 308 \t\t\t#K\n", "T2 = 373. \t\t\t#K\n", "T3 = 538. \t\t\t#K\n", "\n", "# Calculations\n", "e1 = (T2-T1)/T2\n", "e2 = (T3-T1)/T3\n", "\n", "# Results\n", "print 'Efficiency = %.3f '%(e1)\n", "print ' Efficiency = %.3f '%(e2)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Efficiency = 0.174 \n", " Efficiency = 0.428 \n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 7.2 Page No : 139" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "T = 25 \t\t\t#C\n", "T1 = 0. \t\t\t#C\n", "h = 79.8 \t\t\t#cal g**-1\n", "j = 4.18*10**7 \t\t\t#ergs\n", "\n", "# Calculations\n", "Wc = (T-T1)*h/(273+T1)\n", "W = (T-T1)*h*j/(273+T1)\n", "\n", "# Results\n", "print 'Work required = %.1f cal'%(Wc)\n", "print ' Work required = %.2e ergs'%(W)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Work required = 7.3 cal\n", " Work required = 3.05e+08 ergs\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 7.3 Page No : 151" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "import math \n", "R = 1.98 \t\t\t#cal\t\t\t#mol K\n", "x = 0.75\n", "n = 9\n", "\n", "# Calculations\n", "dS = -R*(n*(x/n)*math.log(x/n)+(1-x)*math.log(1-x))\n", "\n", "# Results\n", "print 'Entropy = %.2f cal deg**-1 mole**-1'%(dS)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Entropy = 4.38 cal deg**-1 mole**-1\n" ] } ], "prompt_number": 3 }, { "cell_type": "code", "collapsed": false, "input": [], "language": "python", "metadata": {}, "outputs": [] } ], "metadata": {} } ] }