{ "metadata": { "name": "", "signature": "sha256:13323936ef2e62d44534d1e2a20550e892e59337bee53263e64e756951d19fc1" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 3 : The first law of thermodynamics" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 3.1 Page No : 34" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "p = 1.013*10**6 \t\t\t#dynecm**2\n", "T = 273.16 \t\t\t#K\n", "V = 773.4 \t\t\t#cc\n", "n = 0.0687 \t\t\t#cal\n", "#CALCCULATIONS\n", "W = p*V/T\n", "k = W/n\n", "\n", "# Results\n", "print 'Work of expansion = %.2e ergs'%(W)\n", "print ' 1 cal = %.2e ergs'%(k)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Work of expansion = 2.87e+06 ergs\n", " 1 cal = 4.17e+07 ergs\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 3.2 Page No : 44" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "import math \n", "R = 8.314*10**7 \t\t\t#J/mol K\n", "T = 298.2 \t \t\t#K\n", "p1 = 1. \t\t\t#atm\n", "p2 = 5.\t \t\t #atm\n", "\n", "# Calculations\n", "W = R*T*math.log(p1/p2)\n", "\n", "# Results\n", "print 'Work of expansion = %.2e ergs mole**-1 '%(W)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Work of expansion = -3.99e+10 ergs mole**-1 \n" ] } ], "prompt_number": 2 }, { "cell_type": "code", "collapsed": false, "input": [], "language": "python", "metadata": {}, "outputs": [] } ], "metadata": {} } ] }