{ "metadata": { "name": "", "signature": "sha256:7896b33251e7015813ab8cc120828b27506a0ecc4b27e995a44efccaece33084" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 2 : Properties of thromodynamic systems" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2.1 Page No : 24" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "T = 40 \t\t\t#C\n", "R = 0.0820 \t\t\t#lit-atm deg**-1 mol**-1\n", "v = 0.381 \t\t\t#lit\n", "b = 0.043 \t\t\t#lit\n", "a = 3.6 \n", "\n", "# Calculations\n", "P = (R*(273+T)/(v-b))-(a/v**2)\n", "\n", "# Results\n", "print 'Pressure = %.1f atm'%(P)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Pressure = 51.1 atm\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2.2 Page No : 24" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "T = 0 \t \t\t#C\n", "R = 0.0820 \t\t\t#lit-atm deg**-1 mol**-1\n", "p = 400. \t\t\t#atm\n", "\n", "# Calculations\n", "V = R*(273+T)/p\n", "\n", "# Results\n", "print 'Volume of the ideal gas = %.4f lit mol**-1'%(V)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Volume of the ideal gas = 0.0560 lit mol**-1\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2.3 Page No : 29" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "p = 400. \t\t\t#atm\n", "T = 273 \t \t\t#K\n", "R = 0.0820 \t\t\t#lit-atm deg**-1 mol**-1\n", "k = 1.27\n", "\n", "# Calculations\n", "V = k*R*T/p\n", "\n", "# Results\n", "print 'Volume of the ideal gas = %.3f lit mol**-1'%(V)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Volume of the ideal gas = 0.071 lit mol**-1\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2.4 Page No : 29" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "V = 0.381 \t\t\t#lit\n", "T = 313. \t\t\t#K\n", "R = 0.0820 \t\t\t#lit-atm deg**-1 mol**-1\n", "pc = 72.9 \t\t\t#atm\n", "\n", "# Calculations\n", "p = R*T/V\n", "r = p/pc\n", "\n", "# Results\n", "print 'Pressure of carbon dioxide gas = %.1f atm'%(p)\n", "print ' ratio = %.3f '%(r)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Pressure of carbon dioxide gas = 67.4 atm\n", " ratio = 0.924 \n" ] } ], "prompt_number": 4 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2.5 Page No : 30" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "n1 = 0.25 \t\t\t#mole\n", "n2 = 0.75 \t\t\t#mole\n", "l = 0.0832 \t\t\t#lit\n", "T = 50 \t\t\t#C\n", "p1 = 404 \t\t\t#atm\n", "p2 = 390 \t\t\t#atm\n", "\n", "# Calculations\n", "P = n1*p1+n2*p2\n", "\n", "# Results\n", "print 'Total Pressure = %.f atm'%(P)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Total Pressure = 394 atm\n" ] } ], "prompt_number": 5 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2.6 Page No : 31" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "# Variables\n", "n1 = 0.25 \t\t\t#mole\n", "nh = 0.75 \t\t\t#mole\n", "p = 400. \t\t\t#atm\n", "T = 50. \t\t\t#C\n", "vn = 0.083 \t\t\t#lit\n", "vh = 0.081 \t\t\t#lit\n", "\n", "# Calculations\n", "V = n1*vn+vh*nh\n", "\n", "# Results\n", "print 'Volume of given mixture is = %.3f lit'%(V)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Volume of given mixture is = 0.082 lit\n" ] } ], "prompt_number": 6 }, { "cell_type": "code", "collapsed": false, "input": [], "language": "python", "metadata": {}, "outputs": [] } ], "metadata": {} } ] }