{ "metadata": { "name": "", "signature": "sha256:79ebced3b14c5bbd0f1f1f599d71ac5841752e19c3ef6de2a5a4223855b1a785" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 8 :\n", "applications of statistical\n", "thermodynamics" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.1 pg : 202" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "T = 70. \t\t\t#K\n", "Tr = 85.5 \t\t\t#K\n", "\t\t\t\n", "# Calculations\n", "cvrot = 1.1\n", "cvtra = 1.5\n", "cv = cvtra+cvrot\n", "\t\t\t\n", "# Results\n", "print \"Cv total = %.1f R\"%(cv)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Cv total = 2.6 R\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.2 pg : 202" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "T = 2000. \t\t\t#K\n", "Tr = 3340. \t\t\t#K\n", "\t\t\t\n", "# Calculations\n", "print (\"From fig 8.2\")\n", "cvrot = 0.85\n", "cvtra = 1.5\n", "cvvib = 1.\n", "cv = cvtra+cvrot+cvvib\n", "\t\t\t\n", "# Results\n", "print \"Cv total = %.2f R\"%(cv)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "From fig 8.2\n", "Cv total = 3.35 R\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.3 pg : 208" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "T = 200. \t\t\t#K\n", "the = 398. \t\t\t#K\n", "\t\t\t\n", "# Calculations\n", "ratio = T/the\n", "cv = 4.9\n", "\t\t\t\n", "# Results\n", "print \"Specific heat of aluminium = %.1f cal/g mol K\"%(cv)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Specific heat of aluminium = 4.9 cal/g mol K\n" ] } ], "prompt_number": 3 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.4 pg : 208" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "T = 10. \t\t\t#K\n", "td = 315. \t\t\t#K\n", "\t\t\t\n", "# Calculations\n", "cv = 464.4 *(T/td)**3\n", "\t\t\t\n", "# Results\n", "print \"specific heat of copper = %.5f cal/g mol K\"%(cv)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "specific heat of copper = 0.01486 cal/g mol K\n" ] } ], "prompt_number": 4 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.5 pg : 213" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "import math \n", "N0 = 6.025*10**23\n", "M = 63.57 \n", "d = 8.94 \t\t\t#g/cc\n", "h = 6.624*10**-27\n", "me = 9.1*10**-28\n", "\t\t\t\n", "# Calculations\n", "NbyV = N0*d/M\n", "mu0 = h**2 *(3*NbyV/ math.pi)**(2./3) /(8*me)\n", "e0 = 0.6*mu0*10**-7\n", "Teq = 2*e0/(3*1.38*10**-23)\n", "\t\t\t\n", "# Results\n", "print \"Equivalent temperature = %d K\"%(Teq)\n", "\n", "# check using calculator" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Equivalent temperature = 32681 K\n" ] } ], "prompt_number": 6 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.6 pg : 214" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "import math \n", "T = 300. \t\t\t#K\n", "mu = 1.13*10**-18\n", "k = 1.38*10**-23\n", "\t\t\t\n", "# Calculations\n", "cv = math.pi**2 *k*T/(2*mu)\n", "\t\t\t\n", "# Results\n", "print \"Electron contribution = %.4f R\"%(cv)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Electron contribution = 0.0181 R\n" ] } ], "prompt_number": 7 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.7 pg : 223" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\t\t\t\n", "# Variables\n", "sig = 5.668*10**-5\n", "T1 = 1000. \t\t\t#K\n", "T2 = 2000. \t\t\t#K\n", "\t\t\t\n", "# Calculations\n", "Eb1 = sig*T1**4 *10**-7\n", "Eb2 = sig*T2**4 *10**-7\n", "\t\t\t\n", "# Results\n", "print \"total energy emitted in case 1 = %.3f Watts/cm**2\"%(Eb1)\n", "print \" total energy emitted in case 2 = %.3f Watts/cm**2\"%(Eb2)\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "total energy emitted in case 1 = 5.668 Watts/cm**2\n", " total energy emitted in case 2 = 90.688 Watts/cm**2\n" ] } ], "prompt_number": 8 } ], "metadata": {} } ] }