{ "metadata": { "name": "", "signature": "sha256:07e7b9e13f5186e21c37c016dc92fe3d2ec9f35cd561874f30d6be57401876f8" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 6 Real Gas and Transport Processes in gas" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "EXample 6.1 Page no 89" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#given\n", "a=(2.1*10**-2) #Vanderwaals constant a for neon gas in Nm^4/mol^2\n", "b=(1.71*10**-5) #Vanderwaals constant b for neon gas in m^3/mol\n", "R=8.314 #Gas constant in J/mol.K\n", "\n", "#Calculations\n", "Tc=(8*a)/(27*b*R)\n", "Vc=(3*b)/10.0**-5\n", "Pc=(a/(27*b**2))/10.0**6\n", "\n", "#Output \n", "print\"Critical temperature is \",round(Tc,2),\"K\" \n", "print\"Critical volume is \",round(Vc,2),\"* 10**-5 m**3/mol\"\n", "print\"Critical pressure is \",round(Pc,3),\"* 10**6 N/m**2\"\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Critical temperature is 43.77 K\n", "Critical volume is 5.13 * 10**-5 m**3/mol\n", "Critical pressure is 2.66 * 10**6 N/m**2\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 6.2 Page no 89" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#given\n", "n=181*10**-6 #Coefficient of viscosity of a gas in p\n", "v=3*10**4 #Average speed of molecules in cm/s\n", "d=1.2929*10**-3 #Density in g/cm^3\n", "\n", "#Calculations\n", "lembda=((3*n)/(d*v))/10**-6\n", "\n", "#Output\n", "print\"Mean free path is \",round(lembda,0),\"* 10^-6 cm\"\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Mean free path is 14.0 * 10^-6 cm\n" ] } ], "prompt_number": 3 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 6.3 Page no 89" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#given\n", "m=(28*1.66*10**-27) #Molecular mass of a gas in kg\n", "d=(3.48*10**-10) #Diameter in m\n", "k=(1.38*10**-23) #Boltzmans constant in J/K\n", "P=1.01*10**5 #Pressure at STP in N/m^2\n", "T=273 #Temperature at STP in K\n", "\n", "#Calculations\n", "import math\n", "D=((1/(P*3*d**2*math.sqrt(m)))*((2*k*T)/3.14)**(3/2.0))/10.0**-5\n", "\n", "#Output\n", "print\"Diffusion coefficient of a gas at STP is \",round(D,2),\"* 10**-5 m^2/s\"\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Diffusion coefficient of a gas at STP is 1.49 * 10**-5 m^2/s\n" ] } ], "prompt_number": 5 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 6.4 Page no 89" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#given\n", "m=(32*1.66*10**-27) #Molecular mass of a gas in kg\n", "d=(3.65*10**-10) #Diameter in m\n", "k=(1.38*10**-23) #Boltzmans constant in J/K\n", "P=1.01*10**5 #Pressure at STP in N/m^2\n", "T=273 #Temperature at STP in K\n", "\n", "#Calculations\n", "import math\n", "n=((1/(3.14*d**2))*math.sqrt((8*k*T*m)/(9*3.14)))/10**-5\n", "\n", "#Output\n", "print\"Viscosity of a gas at STP is \",round(n,3),\"*10^-5 N.s/m^2\"\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Viscosity of a gas at STP is 1.799 *10^-5 N.s/m^2\n" ] } ], "prompt_number": 7 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 6.5 Page no 89" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#given\n", "v=460 #Average speed of molecules in m/s\n", "l=(720*10**-10) #Mean free path in m\n", "Cv=21.06 #Specific heat at constant volume in J/K.mol\n", "k=(1.38*10**-23) #Boltzmans constant in J/K\n", "P=1.01*10**5 #Pressure at STP in N/m^2\n", "T=273 #Temperature at STP in K\n", "N=6.022*10**23 #Avagadro constant\n", "\n", "#Calculations\n", "K=((1/3.0)*(Cv/N)*(P/(k*T))*v*l)/10.0**-2\n", "\n", "#Output\n", "print\"Thermal conductivity of the gas at STP is \",round(K,5),\"*10**-2 W/m-K\"\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Thermal conductivity of the gas at STP is 1.03506 *10**-2 W/m-K\n" ] } ], "prompt_number": 10 } ], "metadata": {} } ] }