{ "cells": [ { "cell_type": "markdown", "metadata": {}, "source": [ "# Chapter 26: Energy levels and Spectra" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## Ex26.1:pg-1208" ] }, { "cell_type": "code", "execution_count": 1, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "The ionization energy of the hydrogen atom is E= 13.6 eV\n" ] } ], "source": [ " #Example 26_1\n", "import math \n", " \n", "#To find the ionization energy of the hydrogen atom\n", "e=13.6 #units in eV\n", "print \"The ionization energy of the hydrogen atom is E=\",round(e,1),\" eV\"\n" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## Ex26.2:pg-1209" ] }, { "cell_type": "code", "execution_count": 2, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "The wavelength of fourth line in Paschen series is= 1002.0 nm\n" ] } ], "source": [ " #Example 26_2\n", "import math \n", " #To find the wavelength of fourth line in Paschen series\n", "n1=3 #Units in constant\n", "n2=7 #Units in constant\n", "r=1.0974*10**7 #units in meter**-1\n", "lamda=round((1/r)*((n1**2*n2**2)/(n2**2-n1**2))*10**9) #Units in nm\n", "print \"The wavelength of fourth line in Paschen series is=\",round(lamda),\" nm\"\n" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## Ex26.3:pg-1209" ] }, { "cell_type": "code", "execution_count": 3, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "The energy associated with line 1 is E1= -54.4 eV\n", "The energy associated with line 2 is E2= -13.6 eV\n", "The energy associated with line 3 is E3= -6.04 eV\n", "\n", "The first line of balmer series is lamda= 163.0 nm and belongs to the ultraviolet region\n" ] } ], "source": [ " #Example 26_3\n", "import math \n", " \n", " #To draw the energy level diagram and the find the first line of balmer type series\n", "n=1\n", "e1=-54.4/n**2 #units in ev\n", "n=2\n", "e2=-54.4/n**2 #units in ev\n", "n=3\n", "e3=-54.4/n**2 #units in ev\n", "print \"The energy associated with line 1 is E1=\",round(e1,1),\" eV\\nThe energy associated with line 2 is E2=\",round(e2,1),\" eV\\nThe energy associated with line 3 is E3=\",round(e3,2),\" eV\\n\"\n", "e1=1 #units in eV\n", "e2=7.6 #Units in eV\n", "lamda1=1240 #units in nm\n", "lamda=(e1/e2)*lamda1 #Units in nm\n", "print \"The first line of balmer series is lamda=\",round(lamda),\" nm and belongs to the ultraviolet region\"\n" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## Ex26.4:pg-1209" ] }, { "cell_type": "code", "execution_count": 4, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "The longest wavelength of light capable of ionizing hydrogen atom is lamda= 91.2 nm\n" ] } ], "source": [ " #Example 26_4\n", "import math \n", " \n", " #To find the longest wavelength of light capable of ionizing hydrogen atom\n", " #First method\n", "R=1.097*10**7 #Units in meter**-1\n", "lamda=(1/R)*10**9 #Units in meters\n", " #Second method\n", "E=13.6 #units in eV\n", "e1=1 #units in eV\n", "lamda3=1240.0 #Units in eV\n", "lamda2=(e1/E)*(lamda3) #Units in nm\n", "print \"The longest wavelength of light capable of ionizing hydrogen atom is lamda=\",round(lamda2,1),\" nm\"\n" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## Ex26.5:pg-1210" ] }, { "cell_type": "code", "execution_count": 5, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "The energy difference between n=1 and n=2 level is E= 17713.0 eV\n" ] } ], "source": [ " #Example 26_5\n", "import math \n", " \n", " #To find the energy difference between the n is 1 and n is 2 level\n", "e1=1 #Units in eV\n", "lamda2=1240 #Units in eV\n", "lamda3=0.07 #Units in eV\n", "e2=lamda2/lamda3 #Units in eV\n", "e=e2-e1 #Units in eV\n", "print \"The energy difference between n=1 and n=2 level is E=\",round(e),\" eV\"\n", " #In textbook answer is prinred wrong as E=18000 eV the correct answer is E=17713 eV \n" ] } ], "metadata": { "kernelspec": { "display_name": "Python 2", "language": "python", "name": "python2" }, "language_info": { "codemirror_mode": { "name": "ipython", "version": 2 }, "file_extension": ".py", "mimetype": "text/x-python", "name": "python", "nbconvert_exporter": "python", "pygments_lexer": "ipython2", "version": "2.7.11" } }, "nbformat": 4, "nbformat_minor": 0 }