{ "metadata": { "name": "", "signature": "sha256:63ceed8607dc113635851a8fc16e00b5a679fa077f828a47388aa54622bce4ae" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 18 - Catalysis" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 1 - pg 472" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#calculate the Volume \n", "#Initialization of variables\n", "V1=0.284 #cm^3 /g\n", "V2=1.43 #cm^3 /g\n", "P1=142.4 #mm\n", "P2=760. #mm\n", "#calculations\n", "z=(1/V1 - 1/V2)/(1/P1 - 1/P2)\n", "invVm=1/V2 - z/P2\n", "Vm=1/invVm\n", "#results\n", "print '%s %.1f %s' %(\"Volume =\",Vm,\"cm^3/g\")\n", "print 'The answer in the textbook is a bit different due to rounding off error.'\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Volume = 20.5 cm^3/g\n", "The answer in the textbook is a bit different due to rounding off error.\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2 - pg 477" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#calculate the total area\n", "#Initialization of variables\n", "Vm=2.86 #cc/g\n", "P=1 #atm\n", "R=82.06 #cm^3 atm/deg mol\n", "T=273.2 #deg\n", "N=6.023*10**23\n", "sigma=16.2*10**-16 #cm^2 /molecule\n", "#calculations\n", "n=P*Vm/(R*T)\n", "A=N*n*sigma\n", "#results\n", "print '%s %.2e %s' %(\"total area =\",A,\" cm^2 (g catalyst)^-1\")\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "total area = 1.24e+05 cm^2 (g catalyst)^-1\n" ] } ], "prompt_number": 2 } ], "metadata": {} } ] }