{ "metadata": { "name": "", "signature": "sha256:a22a4cd44988289c63c9da64c71766c244fd20324a2c5a80b53d48938212c4cc" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 9: Atomic Structure" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 9.1, page no. 300" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "\n", "#Variable declaration\n", "\n", "Ub = 9.27 * 10 ** -24 #(J/T)\n", "B = 1.00 #magnetic field strength (T)\n", "h = 6.58 * 10 ** -16 #Planck's constant (eV.s)\n", "e = 1.6 * 10 ** -19 #electron charge (C)\n", "\n", "#Calculation\n", "\n", "hwl = Ub * B / e\n", "wl = hwl / h\n", "\n", "#results\n", "\n", "print \"The magnetic energy is\",round(hwl/10**-5,2),\"x 10^-5 eV and the Larmor frequency is\",round(wl/10**10,2),\"x 10^10 rad/s.\"\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "The magnetic energy is 5.79 x 10^-5 eV and the Larmor frequency is 8.81 x 10^10 rad/s.\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 9.4, page no. 311" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "#Variable declaration\n", "\n", "l2 = 589.592 #sodium doublet wavelength (nm)\n", "l1 = 588.995 #sodium doublet wavelength (nm)\n", "hc = 1240 #planck's constant X speed of light (eV.nm)\n", "\n", "#Calculation\n", "\n", "dE = hc * (l2-l1)/(l2*l1)\n", "\n", "#Results\n", "\n", "print \"dE =\",round(dE/10**-3,2),\"X 10^-3 eV represents the spin orbit splitting of the initial levels.\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "dE = 2.13 X 10^-3 eV represents the spin orbit splitting of the initial levels.\n" ] } ], "prompt_number": 6 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 9.6, page no. 317" ] }, { "cell_type": "code", "collapsed": false, "input": [ "\n", "import math\n", "\n", "#Variable declaration\n", "\n", "E = -5.14 #Energy of the 3s electron in sodium (eV)\n", "Eh = 13.6 #energy of the 3s electron in hydrogen (eV)\n", "\n", "\n", "#Calculation\n", "\n", "Zeff = 3 * math.sqrt(-E/Eh)\n", "\n", "#Results\n", "\n", "print \"Zeff for the 3s electron in sodium is\",round(Zeff,2)" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Zeff for the 3s electron in sodium is 1.84\n" ] } ], "prompt_number": 10 } ], "metadata": {} } ] }