{ "metadata": { "name": "Chapter8" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 8:Many Electron Atoms" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.1 Page 248" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#initiation of variable\n", "hc=1240.0*10**-9;Rinfi=1.097*10**7;Z=11; #for sodium atom;and other constants in MeV\n", "\n", "#calculation\n", "delE=3*hc*Rinfi*(Z-1)**2/4.0 #change in energy\n", "\n", "#result\n", "print\"The energy of the Ka x-ray of the sodium atom in KeV.is\",round(delE/10**3,3);\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "The energy of the Ka x-ray of the sodium atom in KeV.is 1.02\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.2 Page 249" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#initiation of variable\n", "EKa=21.990;EKb=25.145;EK=25.514 #all the values are in KeV\n", "\n", "#calcualtion\n", "ELo=EKb-EKa;\n", "\n", "#result\n", "print\"The energy of La of X-ray in KeV.is\",round(ELo,3); #Energy of La X-ray\n", "\n", "#partb\n", "EL=-EK+EKa;\n", "\n", "#result\n", "print\"Hence the binding energy of the L electon in KeV.is\",round(EL,3); # for electron L electron" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "The enrgy of La of X-ray in KeV.is 3.155\n", "Hence the binding energy of the L electon in KeV.is -3.524\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.3 Page 250" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#initiation of variable\n", "l=1.0; \n", "\n", "#calculation\n", "Lmax=l+l;Lmin=l-l;\n", "s=1.0/2; Smax=s+s;Smin=s-s;\n", "\n", "#result\n", "print\"Value of L ranges from\",Lmin,\" to\",Lmax,\" i.e\",Lmin,1,Lmax;\n", "print\"Values of S are maxi,min\",Smax,Smin;\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Value of L ranges from 0.0 to 2.0 i.e 0.0 1 2.0\n", "Values of S are maxi,min 1.0 0.0\n" ] } ], "prompt_number": 5 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8.4 Page 250" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#initiation of variable\n", "l=1.0; \n", "\n", "#calculation\n", "Lmax=l+l;Lmin=l-l;\n", "s=1.0/2; Smax=s+s;Smin=s-s;\n", "\n", "#result\n", "print\"Considering any two electrons,Value of L2e ranges from\",Lmin,\" to\",Lmax,\" i.e\",Lmin,1,Lmax;\n", "print\"Adding the angular momentum of the third electron to L2emax gives the maximum whole angular momentum as 2+1=3; and subtracting it from L2e=1 gives 0\"\n", "print\"Values of S are maxi,min\",Smax,Smin;\n", "print\"Adding and subtracting the spin of third to S2e=1 and S2e=0 respectively gives the spins 3/2 and 1/2 for the 3 electron system.\";" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Considering any two electrons,Value of L2e ranges from 0.0 to 2.0 i.e 0.0 1 2.0\n", "Adding the angular momentum of the third electron to L2emax gives the maximum whole angular momentum as 2+1=3; and subtracting it from L2e=1 gives 0\n", "Values of S are maxi,min 1.0 0.0\n", "Adding and subtracting the spin of third to S2e=1 and S2e=0 respectively gives the spins 3/2 and 1/2 for the 3 electron system.\n" ] } ], "prompt_number": 6 } ], "metadata": {} } ] }