{ "cells": [ { "cell_type": "markdown", "metadata": {}, "source": [ "#5: Electron theory of metals" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.1, Page number 5.27" ] }, { "cell_type": "code", "execution_count": 35, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "temperature is 1260.84 K\n", "answer varies due to rounding off errors\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "fE=1/100; #probability(%)\n", "E_EF=0.5; #fermi energy(eV)\n", "Kb=1.38*10**-23; #boltzmann constant\n", "e=6.24*10**18; #conversion faction from J to eV\n", "\n", "#Calculation\n", "x=E_EF/(Kb*e);\n", "y=math.log(1/fE);\n", "T=x/y; #temperature(K)\n", "\n", "#Result\n", "print \"temperature is\",round(T,2),\"K\"\n", "print \"answer varies due to rounding off errors\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.2, Page number 5.28" ] }, { "cell_type": "code", "execution_count": 36, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "total number of free electrons is 8.3954 **10**28 per m**3\n", "answer varies due to rounding off errors\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "Ef=7*1.602*10**-19; #fermi energy(J)\n", "h=6.63*10**-34; #planck's constant\n", "m=9.11*10**-31; #mass(kg)\n", "\n", "#Calculation\n", "x=h**2/(8*m);\n", "y=(3/math.pi)**(2/3);\n", "n23=Ef/(x*y);\n", "n=n23**(3/2); #total number of free electrons(per m**3)\n", "\n", "#Result\n", "print \"total number of free electrons is\",round(n/10**28,4),\"**10**28 per m**3\"\n", "print \"answer varies due to rounding off errors\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.3, Page number 5.28" ] }, { "cell_type": "code", "execution_count": 38, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "relaxation time is 39.742 *10**-15 s\n", "answer varies due to rounding off errors\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "rho=1.54*10**-8; #resistivity of metal(ohm m)\n", "n=5.8*10**28; #number of free electrons(per m**3)\n", "e=1.602*10**-19; #charge(c)\n", "m=9.11*10**-31; #mass(kg)\n", "\n", "#Calculation\n", "tow=m/(n*e**2*rho); #relaxation time(s)\n", "\n", "#Result\n", "print \"relaxation time is\",round(tow*10**15,3),\"*10**-15 s\"\n", "print \"answer varies due to rounding off errors\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.4, Page number 5.29" ] }, { "cell_type": "code", "execution_count": 39, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "relaxation time is 3.82 *10**-14 s\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "rho=1.43*10**-8; #resistivity of metal(ohm m)\n", "n=6.5*10**28; #number of free electrons(per m**3)\n", "e=1.6*10**-19; #charge(c)\n", "m=9.1*10**-31; #mass(kg)\n", "\n", "#Calculation\n", "tow=m/(n*e**2*rho); #relaxation time(s)\n", "\n", "#Result\n", "print \"relaxation time is\",round(tow*10**14,2),\"*10**-14 s\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.5, Page number 5.29" ] }, { "cell_type": "code", "execution_count": 42, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "number of conduction electrons is 1.8088 *10**29 per m**3\n", "mobility of electrons is 0.00128 m**2/Vs\n", "drift velocity is 2.3 *10**-4 m/s\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "L=5; #length(m)\n", "R=0.06; #resistance(ohm)\n", "I=15; #current(A)\n", "ne=3; #number of electrons\n", "rho=2.7*10**-8; #resistivity(ohm m)\n", "w=26.98; #atomic weight\n", "D=2.7*10**3; #density(kg/m**3)\n", "Na=6.025*10**26; #avagadro number(per k mol)\n", "\n", "#Calculation\n", "n=ne*Na*D/w; #number of conduction electrons(per m**3)\n", "mew=1/(n*e*rho); #mobility of electrons(m**2/Vs)\n", "vd=I*R/(L*rho*n*e); #drift velocity(m/s)\n", "\n", "#Result\n", "print \"number of conduction electrons is\",round(n/10**29,4),\"*10**29 per m**3\"\n", "print \"mobility of electrons is\",round(mew,5),\"m**2/Vs\"\n", "print \"drift velocity is\",round(vd*10**4,1),\"*10**-4 m/s\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.6, Page number 5.30" ] }, { "cell_type": "code", "execution_count": 43, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "mobility of electrons is 0.00427 m**2/Vs\n", "answer in the book is wrong\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "ne=1; #number of electrons\n", "rho=1.73*10**-8; #resistivity(ohm m)\n", "w=63.5; #atomic weight\n", "e=1.6*10**-19; #charge(c)\n", "D=8.92*10**3; #density(kg/m**3)\n", "Na=6.02*10**26; #avagadro number(per k mol)\n", "\n", "#Calculation\n", "n=ne*Na*D/w;\n", "mew=1/(n*e*rho); #mobility of electrons(m**2/Vs)\n", "\n", "#Result\n", "print \"mobility of electrons is\",round(mew,5),\"m**2/Vs\"\n", "print \"answer in the book is wrong\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.7, Page number 5.31" ] }, { "cell_type": "code", "execution_count": 44, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "mobility of electrons is 0.00428 m**2/Vs\n", "answer in the book is wrong\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "ne=1; #number of electrons\n", "rho=1.721*10**-8; #resistivity(ohm m)\n", "w=63.54; #atomic weight\n", "e=1.6*10**-19; #charge(c)\n", "D=8.95*10**3; #density(kg/m**3)\n", "Na=6.025*10**26; #avagadro number(per k mol)\n", "\n", "#Calculation\n", "n=ne*Na*D/w;\n", "mew=1/(n*e*rho); #mobility of electrons(m**2/Vs)\n", "\n", "#Result\n", "print \"mobility of electrons is\",round(mew,5),\"m**2/Vs\"\n", "print \"answer in the book is wrong\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.8, Page number 5.31" ] }, { "cell_type": "code", "execution_count": 48, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "relaxation time is 3.64 *10**-14 s\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "rho=1.5*10**-8; #resistivity of metal(ohm m)\n", "n=6.5*10**28; #number of free electrons(per m**3)\n", "e=1.602*10**-19; #charge(c)\n", "m=9.11*10**-31; #mass(kg)\n", "\n", "#Calculation\n", "tow=m/(n*e**2*rho); #relaxation time(s)\n", "\n", "#Result\n", "print \"relaxation time is\",round(tow*10**14,2),\"*10**-14 s\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.9, Page number 5.32" ] }, { "cell_type": "code", "execution_count": 49, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "relaxation time is 3.97 *10**-14 s\n", "drift velocity is 0.7 m/s\n", "mobility is 0.7 *10**-2 m**2/Vs\n", "thermal velocity is 1.17 *10**5 m/s\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "rho=1.54*10**-8; #resistivity of metal(ohm m)\n", "n=5.8*10**28; #number of free electrons(per m**3)\n", "e=1.602*10**-19; #charge(c)\n", "m=9.11*10**-31; #mass(kg)\n", "E=1*10**2; #electric field(V/m)\n", "Kb=1.381*10**-23; #boltzmann constant\n", "T=300; #temperature(K)\n", "\n", "#Calculation\n", "tow=m/(n*e**2*rho); #relaxation time(s)\n", "vd=e*E*tow/m; #drift velocity(m/s)\n", "mew=vd/E; #mobility(m**2/Vs)\n", "Vth=math.sqrt(3*Kb*T/m); #thermal velocity(m/s)\n", "\n", "#Result\n", "print \"relaxation time is\",round(tow*10**14,2),\"*10**-14 s\"\n", "print \"drift velocity is\",round(vd,1),\"m/s\"\n", "print \"mobility is\",round(mew*10**2,1),\"*10**-2 m**2/Vs\"\n", "print \"thermal velocity is\",round(Vth/10**5,2),\"*10**5 m/s\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.10, Page number 5.32" ] }, { "cell_type": "code", "execution_count": 50, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "fermi velocity is 1.39 *10**6 m/s\n", "mean free path is 5.52 *10**-8 m\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "EF=5.5*1.602*10**-19; #fermi energy of silver(J)\n", "tow=3.97*10**-14; #relaxation time(s)\n", "m=9.11*10**-31; #mass(kg)\n", "\n", "#Calculation\n", "vf=math.sqrt(2*EF/m); #fermi velocity(m/s)\n", "lamda=vf*tow; #mean free path(m)\n", "\n", "#Result\n", "print \"fermi velocity is\",round(vf/10**6,2),\"*10**6 m/s\"\n", "print \"mean free path is\",round(lamda*10**8,2),\"*10**-8 m\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.11, Page number 5.33" ] }, { "cell_type": "code", "execution_count": 52, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "fermi energy is 8.83 *10**-19 J\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "ne=1; #number of electrons\n", "M=107.9; #atomic weight\n", "D=10500; #density(kg/m**3)\n", "Na=6.025*10**26; #avagadro number(per k mol)\n", "m=9.11*10**-31; #mass(kg)\n", "h=6.63*10**-34; #planck's constant\n", "\n", "#Calculation\n", "n=ne*Na*D/M; \n", "x=h**2/(8*m);\n", "y=(3/math.pi)**(2/3);\n", "Ef=x*y*n**(2/3); #fermi energy(eV) \n", "\n", "#Result\n", "print \"fermi energy is\",round(Ef*10**19,2),\"*10**-19 J\"" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "##Example number 5.12, Page number 5.33" ] }, { "cell_type": "code", "execution_count": 58, "metadata": { "collapsed": false }, "outputs": [ { "name": "stdout", "output_type": "stream", "text": [ "drift velocity of free electrons is 0.7391 *10**-3 m/s\n" ] } ], "source": [ "#importing modules\n", "import math\n", "from __future__ import division\n", "\n", "#Variable declaration\n", "A=10*10**-6; #area(m**2)\n", "ne=1; #number of electrons\n", "I=100; #current(amperes)\n", "w=63.5; #atomic weight\n", "e=1.6*10**-19; #charge(c)\n", "D=8.92*10**3; #density(kg/m**3)\n", "Na=6.02*10**26; #avagadro number(per k mol)\n", "\n", "#Calculation\n", "n=ne*Na*D/w;\n", "J=I/A;\n", "vd=J/(n*e); #drift velocity of free electrons(m/s)\n", "\n", "#Result\n", "print \"drift velocity of free electrons is\",round(vd*10**3,4),\"*10**-3 m/s\"" ] } ], "metadata": { "kernelspec": { "display_name": "Python 2", "language": "python", "name": "python2" }, "language_info": { "codemirror_mode": { "name": "ipython", "version": 2 }, "file_extension": ".py", "mimetype": "text/x-python", "name": "python", "nbconvert_exporter": "python", "pygments_lexer": "ipython2", "version": "2.7.9" } }, "nbformat": 4, "nbformat_minor": 0 }