{ "metadata": { "name": "" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 2 - Thermodynamics : The first law" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example I1 - Pg 46" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Calculate the change in temperature\n", "#Initialization of variables\n", "Cpm=75 #J/k mol\n", "n=5.55 #mol\n", "q=1 #kJ\n", "#Calculations\n", "deltaT=q*1000/(n*Cpm)\n", "#results\n", "print '%s %.1f %s' %('Change in temperature =',deltaT,'K')\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Change in temperature = 2.4 K\n" ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example I4 - Pg 52" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Calculate the change in enthalpy of the sample\n", "#Initialization of variables\n", "n=5.55 #mol\n", "T1=20 #C\n", "T2=80 #K\n", "Cpm=75.29 #J/K mol\n", "#Calculations\n", "H=n*Cpm*(T2-T1)/1000.\n", "#results\n", "print '%s %d %s' %('Enthalpy of the sample changes by',H,'kJ')\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Enthalpy of the sample changes by 25 kJ\n" ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example E1 - Pg 45" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Calculate the heat supplied, heat capacity and heat output of the calorimeter\n", "#Initialization of variables\n", "A=1.23 #A\n", "V=12 #V\n", "t=123 #s\n", "Temp=4.47 #C\n", "rise=3.22 #C\n", "#Calculations\n", "q=A*V*t\n", "C=q/Temp\n", "Output= C*rise/1000.\n", "#Results\n", "print '%s %.1f %s' %('heat supplied during calibration =',q,'J')\n", "print '%s %.1f %s' %('\\n Heat capacity of the calorimeter =',C,'J/C')\n", "print '%s %.2f %s' %('\\n Heat output =',Output,' kJ')\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "heat supplied during calibration = 1815.5 J\n", "\n", " Heat capacity of the calorimeter = 406.1 J/C\n", "\n", " Heat output = 1.31 kJ\n" ] } ], "prompt_number": 3 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example E2 - Pg 48" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Calculate the amount by which the person's internal energy falls\n", "#Initialization of variables\n", "work=-622 #kJ\n", "heat=-82 #kJ\n", "#Calculations\n", "U=work+heat\n", "#results\n", "print '%s %d %s' %('The persons internal energy falls by',-U,'kJ')\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "The persons internal energy falls by 704 kJ\n" ] } ], "prompt_number": 2 } ], "metadata": {} } ] }