{ "metadata": { "name": "", "signature": "sha256:4f8260f1b2df9e05157c56dfea1a72ed7a44f559ce07767048b00c505967ad51" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 7: Availability and General Thermodynamic Relations" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 1, page no. 230" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "p1 = 1.6 #Pressure of entering steam(in MPa):\n", "T1 = 300+273 #Temperature of entering steam(in K):\n", "p2 = 0.1 #Pressure of leaving steam(in MPa):\n", "T2 = 150+273 #Temperature of leaving steam(in K):\n", "c2 = 150 #Velocity of the leaving steam(in m/s):\n", "m = 2.5 #Mass flow rate(in kg/s):\n", "#From steam tables:\n", "h1 = 3034.8 #kJ/kg\n", "s1 = 6.8844 #kJ/kg.K\n", "h2 = 2776.4 #kJ/kg\n", "s2 = 7.6134 #kJ/kg.K\n", "\n", "#Calculations:\n", "T0 = 15+273 #Surrounding temperature(in K):\n", "Wmax = (h1-h2)-T0*(s1-s2)-(c2**2)/2*10**(-3) #Maxiimum work possible(in kW):\n", "\n", "#Results:\n", "print \"Maximum work possible: \",round(m*Wmax,2),\"kW\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Maximum work possible: 1142.76 kW\n" ] } ], "prompt_number": 3 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 2, page no. 231" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "from math import log\n", "\n", "#Variable Declaration: \n", "pa = 1 #Pressure of air(in bar) for tank A:\n", "m = 1 #Mass of air(in kg):\n", "Cv = 0.717 #Value of Cv(in kJ/kg.K):\n", "T = 50+273 #Temperature(in K):\n", "R = 0.287 #Gas costant(in kJ/kg.K):\n", "p0 = 1 #Atmospheric pressure(in bar):\n", "T0 = 15+273 #Atmosphere temperature(in K):\n", "Cp = 1.004 #Value of Cp(in kJ/kg.K):\n", "pb = 3 #Pressure(in bar) for tank B:\n", "\n", "#Calculations:\n", "AA = m*(Cv*(T-T0)+R*(p0/pa*T-T0)-T0*Cp*log(T/T0)+T0*R*log(pa/p0)) #Availability of air in tank A(in kJ):\n", "AB = m*(Cv*(T-T0)+R*(p0/pb*T-T0)-T0*Cp*log(T/T0)+T0*R*log(pb/p0)) #Availability of air in tank B(in kJ):\n", "\n", "#Results:\n", "print \"Availabiltiy of air in tank A: \",round(AA,2),\"kJ\"\n", "print \"Availability of air in tank B: \",round(AB,2),\"kJ\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Availabiltiy of air in tank A: 1.98 kJ\n", "Availability of air in tank B: 30.98 kJ\n" ] } ], "prompt_number": 4 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 3, page no. 232" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "m = 15 #Mass of steam(in kg):\n", "p1 = 10 #Pressure of entering steam(in bar):\n", "T1 = 300+273 #Temperature(in K):\n", "p2 = 0.05 #Pressure of leaving steam(in bar): \n", "x = 0.95 #Dryness fraction:\n", "v2 = 160 #Velocity(in m/s):\n", "p0 = 1 #Atmosheric pressure(in bar):\n", "T0 = 15+273 #Atmospheric temperature(in K):\n", "#From steam tables:\n", "h1 = 3051.2 #kJ/kg\n", "s1 = 7.1229 #kJ/kg.K\n", "sf = 0.4764 #kJ/kg.K\n", "sfg = 7.9187 #kJ/kg.K\n", "hf = 137.82 #kJ/kg\n", "hfg = 2423.7 #kJ/kg\n", "h0 = 62.99 #kJ/kg\n", "s0 = 0.2245 #kJ/kg.K\n", "\n", "#Calculations:\n", "h2 = hf+x*hfg #Enthalpy at exit of turbine(in kJ/kg):\n", "s2 = sf+x*sfg #Entropy at exit of turbine(in kJ/kg.K):\n", "W = (h1-h2)-v2**2/2*10**(-3) #Work output(in kJ/kg):\n", "pW = m*W #Power output(in kW):\n", "Wmax = (h1-T0*s1)-(h2+v2**2/2*10**(-3)-T0*s2) #Maximum work given end states(in kW):\n", "Ae = (h2-h0)+v2**2/2*10**(-3)-T0*(s2-s0) #Maximum wor kavailable from exhaust steam(in kJ/kg):\n", "Wme = m*Ae #Maximum power that could be obtained from exhaust steam(in kW):\n", "\n", "#Results:\n", "print \"Power output: \",round(pW,1), \"kW\" \n", "print \"Maximum power output: \" ,round(m*Wmax,1), \"kW\"\n", "print \"Maximum power from exhaust steam: \",round(Wme,1), \"kW\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Power output: 8971.0 kW\n", "Maximum power output: 12756.4 kW\n", "Maximum power from exhaust steam: 2265.6 kW\n" ] } ], "prompt_number": 5 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 4, page no. 234" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", " \n", "#Variable Declaration: \n", "m = 5 #Mass of steam(in kg):\n", "z1 = 10 #Initial elevation(in m):\n", "V1 = 25 #Initial velocity(in m/s):\n", "z2 = 2 #Final elevation(in m):\n", "V2 = 10 #Final velocity(in m/s):\n", "#Dead state of water\n", "u0 = 104.86 #kJ/kg \n", "v0 = 1.0029*10**(-3)#m3/kg\n", "s0 = 0.3673 #kJ/kg\u00b7K\n", "p0 = 100 #kPa\n", "T0 = 25+273 #K\n", "#Initial state\n", "u1 = 2550 #kJ/kg \n", "v1 = 0.5089 #m3/kg\n", "s1 = 6.93 #kJ/kg\u00b7K\n", "#Final state\n", "u2 = 83.94 #kJ/kg \n", "v2 = 1.0018*10**(-3)#m3/kg\n", "s2 = 0.2966 #kJ/kg\u00b7K\n", "g = 9.81 #Acceleration due to gravity(in m/s**2):\n", "\n", "#Calculation:\n", "A1 = m*((u1-u0)*10**3+p0*10**3*(v1-v0)-T0*(s1-s0)*10**3+V1**2/2+g*z1)#Availability at initial state(in kJ):\n", "A2 = m*((u2-u0)*10**3+p0*10**3*(v2-v0)-T0*(s2-s0)*10**3+V2**2/2+g*z2)#Availability at final state(in kJ):\n", "dA = A2-A1 #Change in availability(in kJ)\n", "\n", "#Results:\n", "print \"Initial availabilty: \",round(A1/10**3,2), \"kJ\"\n", "print \"Final availabilty:\",round(A2/10**3,2),\"kJ\"\n", "print \"Availability decreases by: \",round(-dA/10**3,2), \"kJ\"\t\t\t" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Initial availabilty: 2703.28 kJ\n", "Final availabilty: 1.09 kJ\n", "Availability decreases by: 2702.19 kJ\n" ] } ], "prompt_number": 10 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 6, page no. 235" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "T1 = 800+273 #Temperature of IC engine(in K):\n", "W = 1050 #Work per kg of gas in engine(in kJ/kg):\n", "Cp = 1.1 #Cp of gas(in kJ/kg.K):\n", "\n", "#Calculations:\n", "T0 = 30+273 #Temperature of the surroundings(in K):\n", "dSsys = W/T1 #Change in entropy of system(in kJ/kg.K):\n", "dSsurr = -Cp*(T1-T0)/T0 #Change in entropy of surroundings(in kJ/kg.K):\n", "L = -T0*(dSsys+dSsurr) #Loss of available energy(in kJ/kg):\n", "r = L/W #Ratio of lost available exhaust energy to engine work:\n", "\n", "#Results:\n", "print \"Ratio of available exhaust energy to engine work: \",round(r,3)" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Ratio of available exhaust energy to engine work: 0.524\n" ] } ], "prompt_number": 15 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 7, page no. 236" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "m = 10 #Mass of water(in kg):\n", "T1 = 150+273 #Initial temperature(in K):\n", "V1 = 25 #Initial velocity(in m/s):\n", "z1 = 10 #Initial elevation(in m):\n", "T2 = 20+273 #Final temperature(in K):\n", "V2 = 10 #Final velocity(in m/s):\n", "z2 = 3 #Final elevation(in m):\n", "p0 = 0.1 #Pressure of environment(in MPa):\n", "T0 = 25+273.13 #Temperature of environment(in K):\n", "g = 9.8 #Acceleration due to gravity(in m/s**2):\n", "#Dead state of water, From steam tables:\n", "u0 = 104.88 #kJ/kg\n", "v0 = 1.003*10**(-3) #m3/kg\n", "s0 = 0.3674 #kJ/kg\u00b7K\n", "u1 = 2559.5 #kJ/kg\n", "v1 = 0.3928 #m3/kg\n", "s1 = 6.8379 #kJ/kg\u00b7K\n", "u2 = 83.95 #kJ/kg\n", "v2 = 0.001002 #m3/kg\n", "s2 = 0.2966 #kJ/kg\u00b7K\n", "A1 = m*((u1-u0)+p0*10**3*(v1-v0)-T0*(s1-s0)+(V1**2/2+g*z1)*10**-3)#Availability at initial state(in kJ):\n", "A2 = m*((u2-u0)+p0*10**3*(v2-v0)-T0*(s2-s0)+(V2**2/2+g*z2)*10**-3)#Availability at final state(in kJ):\n", "dA = A2-A1 #Change in availability(in kJ):\n", "\n", "#Results:\n", "print \"Initial availabilty: \",round(A1,2),\"kJ\"\n", "print \"Final availabilty: \",round(A2,2),\"kJ\"\n", "print \"Availability decreases: \",round(-dA,2),\"kJ\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Initial availabilty: 5651.6 kJ\n", "Final availabilty: 2.57 kJ\n", "Availability decreases: 5649.03 kJ\n" ] } ], "prompt_number": 18 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 8, page no. 237" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "m = 5 #Mass flow rate(in kg/s):\n", "#At inlet to turbine,\n", "p1 = 5 #MPa \n", "T1 = 500+273.15 #K\n", "h1 = 3433.8 #kJ/kg\n", "s1 = 6.9759 #kJ/kg.K\n", "#At exit from turbine.\n", "p2 = 0.2 #MPa\n", "T2 = 140+273.15 #K\n", "h2 = 2748 #kJ/kg\n", "s2 = 7.228 #kJ/kg\u00b7K\n", "#At dead state,\n", "p0 = 101.3 #kPa\n", "T0 = 25+273.15 #K\n", "h0 = 104.96 #kJ/kg\n", "s0 = 0.3673 #kJ/kg\u00b7K\n", "Q = 600 #Heat loss(in kJ/s):\n", "\n", "#Calculation:\n", "A1 = m*((h1-h0)-T0*(s1-s0))\t#Availablity of steam at inlet(in kJ):\n", "W = m*(h1-h2)-Q #Turbine output(in kW):\n", "Wmax = m*((h1-h2)-T0*(s1-s2)) #Maximum output(in kW):\n", "I = Wmax-W #Irreversibilty(in kW):\n", "\n", "#Results:\n", "print \"Availability of steam at inlet: \",round(A1,2),\"kJ\"\n", "print \"Turbine output: \",round(W),\"kW\"\n", "print \"Maximum output: \",round(Wmax,2),\"kW\"\n", "print \"Irreversibility: \",round(I,2),\"kW\"\n", "print \"_____Please Check there is a calculation mistake in Wmax hence answer differs_____\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Availability of steam at inlet: 6792.43 kJ\n", "Turbine output: 2829.0 kW\n", "Maximum output: 3804.82 kW\n", "Irreversibility: 975.82 kW\n", "_____Please Check there is a calculation mistake in Wmax hence answer differs_____\n" ] } ], "prompt_number": 20 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 11, page no. 239" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "Q = 500 #Heat removed(in kJ):\n", "T1 = 835 #Temperature of the heat reservoir(in K):\n", "T2 = 720 #Temperature of the system(in K):\n", "T0 = 280 #Temperature of surroundings(in K):\n", "\n", "#Calculation:\n", "A1 = T0*Q/T1 #Availability for heat reservoir(in kJ/kg.K):\n", "A2 = T0*Q/T2 #Availability for system(in kJ/kg.K):\n", "Anet = A1-A2 #Net loss of available energy(in kJ/kg.K):\n", "\n", "#Results:\n", "print \"Loss of available energy: \",round(-Anet,2),\"kJ/kg.K\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Loss of available energy: 26.78 kJ/kg.K\n" ] } ], "prompt_number": 26 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 12, page no. 240" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "h1 = 4142 #Enthalpy at entrance(in kJ/kg):\n", "h2 = 2585 #Enthalpy at exit(in kJ/kg):\n", "A1 = 1787 #Availability of steam at entrance(in kJ/kg):\n", "A2 = 140 #Availability of steam at exit(in kJ):\n", "\n", "#Calculation:\n", "Wmax = A1-A2 #Maximum work possible(in kJ/kg):\n", "Wact = h1-h2 #Actual work from turbine(in kJ/kg):\n", "\n", "#Results:\n", "print \"Actual work: \",round(Wact),\"kJ/kg\" \n", "print \"Maximum possible work: \",round(Wmax),\"kJ/kg\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Actual work: 1557.0 kJ/kg\n", "Maximum possible work: 1647.0 kJ/kg\n" ] } ], "prompt_number": 28 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 13, page no. 240" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", " \n", "#Variable Declaration: \n", "Tmin = 20+273 #Minimum temperature(in K):\n", "Tmax = 500+273 #Maximum temperature(in K):\n", "n = 0.25 #Efficiency of heat engine:\n", "\n", "#Calculations:\n", "nrev = 1-Tmin/Tmax #Reversible engine efficiency:\n", "n2 = n/nrev #Second law efficiency:\n", "\n", "#Result:\n", "print \"Second law efficiency: \",round(n2*100,2),\"%\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Second law efficiency: 40.26 %\n" ] } ], "prompt_number": 30 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 14, page no. 240" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "from math import log\n", "#Variable Declaration: \n", "Va = 6 #Volume of compartment A(in m**3):\n", "Vb = 4 #Volume of compartment B(in m**3):\n", "p1 = 6 #Pressure in compartment A(in bar):\n", "T1 = 600 #Temperature in compartment A(in K):\n", "p0 = 1 #Atmosheric pressure(in bar):\n", "T0 = 300 #Atmosheric temperature(in K):\n", "r = 1.4 #Adiabatic index of compression:\n", "R = 0.287 #Gas constant(in J/kg.K):\n", "Cv = 0.718 #Value of Cv(in kJ/kg.K):\n", "\n", "#Calculation:\n", "V2 = Va+Vb #Final volume(in m**3):\n", "T2 = T1*(Va/V2)**(r-1) #Final temperature(in K):\n", "m = p1*10**5*Va/(R*10**3*T1) #Mass of air(in kg):\n", "dSs = round(m*(Cv*log(T2/T1)+R*log(V2/Va)),3)#Change in entropy of control system(in kJ/kg.K):\n", "I = T0*dSs #Loss of available energy or irreversibilty(in kJ):\n", "\n", "#Results:\n", "print \"Loss of available energy: \",round(-I,3),\"kJ\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Loss of available energy: 0.6 kJ\n" ] } ], "prompt_number": 33 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 16, page no. 242" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", " \n", "#Variable Declaration: \n", "Tmin = 30+273 #Minimum temperature(in K):\n", "Tmax = 700+273 #Maximum temperature(in K):\n", "T0 = 17+273 #Temperature of surroundings(in K):\n", "Q1 = 2*10**4 #Rate at which engine receives heat(in kJ/min):\n", "Wu = 0.13*10**3 #Measured output of the engine(in kW):\n", "\n", "#Calculation:\n", "nrev = 1-Tmin/Tmax #Efficiency:\n", "Wrev = nrev*Q1/60 #Availability or reversible work(in kJ/s):\n", "I = Wrev-Wu #Rate of irreversibility(in kJ/s):\n", "n2 = Wu/Wrev #Second law efficiency:\n", "\n", "#Results:\n", "print \"Availability: \",round(Wrev*60/10**4,2),\" x 10^4 kJ/min\"\n", "print \"Rate of irreversibility: \",round(I,2),\"kW\"\n", "print \"Second Law Efficiency: \",round(n2*100,2),\"%\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Availability: 1.38 x 10^4 kJ/min\n", "Rate of irreversibility: 99.53 kW\n", "Second Law Efficiency: 56.64 %\n" ] } ], "prompt_number": 37 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 17, page no. 242" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", " \n", "#Variable Declaration: \n", "p1 = 1.5 #Initial pressure(in bar):\n", "T1 = 60+273 #Initial temperature(in K):\n", "p2 = 2.5 #Final pressure(in bar):\n", "Tres = 400+273\t \t#Temperature of the reservoir(in K):\n", "T0 = 27+273\t\t#Temperature of surroundings(in K):\n", "Cp = 1.005\t\t#Cp of air(in kJ/kg.K):\n", "\n", "#Calculations:\n", "T2 = T1*p2/p1\t\t#Final temperature(in K):\n", "Q = Cp*(T2-T1)\t\t#Heat addition to air in the tank(in kJ/kg):\n", "dSs = Q/T1\t\t#Change in entropy of the system(in kJ/kg.K):\n", "dSe = -Q/Tres\t\t#Change in entropy of environment(in kJ/kg.K):\n", "dS = dSs+dSe\t\t#Total change in entropy(in kJ/kg.K):\n", "L = T0*dS\t\t#Loss of available energy(in kJ/kg):\n", "\n", "#Results:\n", "print \"Loss of available energy:\",round(L,1),\"kJ/kg.K\"\t\t\t\t" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Loss of available energy: 101.5 kJ/kg.K\n" ] } ], "prompt_number": 39 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 19, page no. 244" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", " \n", "\n", "#Variable Declaration: \n", "#From steam tables:\n", "vg = 0.12736\t\t\t\t\n", "vf = 0.001157\n", "p205 = 1.7230\n", "p195 = 1.3978\n", "T = 200+273\n", "hfga = 1940.7\n", "\n", "#Calculation:\n", "vfg = vg-vf\t\t\t\t#Value of vfg(in m**3/kg):\n", "r = (p205-p195)/(205-195)\t\t#Value of dp/dT(in MPa/K):\n", "hfg = T*vfg*r*10**3\t\t\t#By Clapeyron equation(in kJ/kg):\n", "\n", "#Results:\n", "print \"Calculated enthalpy of vaporization: \",round(hfg,2),\"kJ/kg\"\t\t\t\t\n", "print \"Enthalpy of vaporization from steam table:\",round(hfga,1),\"kJ/kg\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Calculated enthalpy of vaporization: 1941.25 kJ/kg\n", "Enthalpy of vaporization from steam table: 1940.7 kJ/kg\n" ] } ], "prompt_number": 45 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 20, page no. 244" ] }, { "cell_type": "code", "collapsed": false, "input": [ " \n", "from math import log\n", "#Variable Declaration: \n", "#From steam tables:\n", "p5 = 260.96 #kPa\t\t\t\t\n", "p15 = 182.60 #kPa\n", "vg10 = 0.07665 #m**3/kg\n", "vf10 = 0.00070 #m**3/kg\n", "R = 0.06876 #kJ/kg.K\n", "hfg10 = 156.3 #kJ/kg\n", "\n", "#Calculation:\n", "T = -5+273\n", "T1 = -15+273\n", "T2 = -5+273\n", "hfg = T*(vg10-vf10)*(p5-p15)/(15-5)\t#Value of hfg, by Clapeyron equation:\n", "hfg1 = log(p5/p15)*R*(T1*T2)/((T2-T1))\t#By Clapeyron-Clausius equation:\n", "d = (hfg1-hfg)/hfg*100\t\t\t#Deviation:\n", "\n", "#Results:\n", "print \"hfg by Clapeyron equation: \",round(hfg,2),\"kJ/kg\"\t\t\t\t\n", "print \"hfg by Clapeyron-Clausius equation: \",round(hfg1,2),\"kJ/kg\"\n", "print \"Percentage deviation in hfg value by Clapeyron-Clausius equation compared to the value from Clapeyron equation: \",round(d,2),\"%\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "hfg by Clapeyron equation: 159.5 kJ/kg\n", "hfg by Clapeyron-Clausius equation: 169.76 kJ/kg\n", "Percentage deviation in hfg value by Clapeyron-Clausius equation compared to the value from Clapeyron equation: 6.44 %\n" ] } ], "prompt_number": 48 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 21, page no. 245" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "#From steam tables:\n", "v350 = 0.9534\t \n", "v250 = 0.7964\n", "v300 = 0.8753\n", "v350kPa = 0.76505\n", "v250kPa = 1.09575\n", "\n", "#Calculation:\n", "ve = (v350-v250)/(v300*(350-250))\t#Volume expansivity(in 1/K):\n", "ic = -(v350kPa-v250kPa)/(v300*(350-250))#Isothermal compressibility(in 1/kPa):\n", "\n", "#Results:\n", "print \"Volume expansivity: \",round(ve*10**3,4),\"x 10^-3 K^-1\"\t\t\t\t\n", "print \"Isothermal compressibility: \",round(ic*10**3,3),\"x 10^-3 kPa^-1\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Volume expansivity: 1.7937 x 10^-3 K^-1\n", "Isothermal compressibility: 3.778 x 10^-3 kPa^-1\n" ] } ], "prompt_number": 51 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 22, page no. 246" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "from math import log\n", "#Variable Declaration: \n", "V = 0.5\t\t\t\t#Volume of tank(in m**3):\n", "p0 = 1\t\t\t\t#Atmospheric pressure(in bar):\n", "T0 = 25+273\t\t\t#Atmospheric temperature(in K):\n", "Cp = 1.005\t\t\t#Cp of gas(in kJ/kg.K):\n", "Cv = 0.718\t\t\t#Cv of gas(in kJ/kg.K):\n", "Ti = T0\t\t\t\t#Initial temperature(in K):\n", "\n", "#Calculations:\n", "Tf = Cp/Cv*Ti\t\t\t#Inside final temperature(in K):\n", "dSgen = Cp*log(Tf/Ti)\t\t#Change in entropy(in kJ/kg.K):\n", "I = T0*dSgen\t\t\t#Irreversibility(in kJ/kg):\n", "\n", "#Results:\n", "print \"Inside final temperature\",round(Tf,2),\"K\"\t\t\t\t\n", "print \"Change in entropy: \",round(dSgen,4),\"kJ/kg.K\"\n", "print \"Irreversibility\",round(I,2),\"kJ/kg\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Inside final temperature 417.12 K\n", "Change in entropy: 0.338 kJ/kg.K\n", "Irreversibility 100.71 kJ/kg\n" ] } ], "prompt_number": 53 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 23, page no. 246" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "from math import log\n", "#Variable Declaration: \n", "m = 75\t\t\t\t#Mass of water(in kg):\n", "T1 = 400+273\t\t\t#Temperature of hot water(in K):\n", "T2 = 300\t\t\t#Final temperature(in K):\n", "T0 = 27+273\t\t\t#Temperature of the environment(in K):\n", "Cp = 4.18\t\t\t#Specific heat of water(in kJ/kg.K):\n", "\n", "#Calculation:\n", "Wmax = m*Cp*(T1-T2-T0*log(T1/T2))#Maximum work(in kJ):\n", "\n", "#Results:\n", "print \"Maximum work: \",round(Wmax,1),\"kJ\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Maximum work: 40946.6 kJ\n" ] } ], "prompt_number": 57 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example 24, page no. 247" ] }, { "cell_type": "code", "collapsed": false, "input": [ "from __future__ import division\n", "\n", "#Variable Declaration: \n", "p1 = 50\t\t #Pressure at which steam enters(in bar):\n", "T1 = 600+273\t #Temperature at which steam enters(in K):\n", "c1 = 150\t #Velocity at which steam enters(in m/s):\n", "p2 = 0.1\t #Pressure at which steam leaves(in bar):\n", "c2 = 50\t\t #Velocity at which steam leaves(in m/s):\n", "W = 1000\t #Work delivered(in kJ/kg):\n", "T0 = 25+273\t #Dead state temperature(in K):\n", "#From steam tables:\n", "h1 = 3666.5 #kJ/kg\t\t\t\t\n", "s1 = 7.2589 #kJ/kg.K\n", "h2 = 2584.7 #kJ/kg\n", "s2 = 8.1502 #kJ/kg.K\n", "\n", "#Calculations:\n", "A1 = h1+c1**2/2*10**(-3)-T0*s1\t#Inlet stream availability(in kJ/kg):\n", "A2 = h2+c2**2/2*10**(-3)-T0*s2\t#Exit stream availability(in kJ/kg):\n", "Wrev = A1-A2\t\t\t#Reversible work(in kJ/kg):\n", "I = Wrev-W\t\t\t#Irreversibility(in kJ/kg):\n", "\n", "#Results:\n", "print \"Inlet stream availability: \",round(A1,2),\"kJ/kg\"\t\t\t\t\n", "print \"Exit stream availability: \",round(A2,2),\"kJ/kg\"\n", "print \"Irreversibility: \",round(I,1),\"kJ/kg\"" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "Inlet stream availability: 1514.6 kJ/kg\n", "Exit stream availability: 157.19 kJ/kg\n", "Irreversibility: 357.4 kJ/kg\n" ] } ], "prompt_number": 59 } ], "metadata": {} } ] }