{ "metadata": { "name": "" }, "nbformat": 3, "nbformat_minor": 0, "worksheets": [ { "cells": [ { "cell_type": "heading", "level": 1, "metadata": {}, "source": [ "Chapter 3:Lubricants" ] }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:1,Page no:27" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=4.55#weight f oil saponified(gms)#\n", "volume=2.1#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.02#normality of KOH #\n", "\n", "#Calculation\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.517 mg/g\n", ] } ], "prompt_number": 1 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:2,Page no:28" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=10.#weight f oil saponified(gms)#\n", "volume=2.4#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.02#normality of KOH #\n", "\n", "#Calculation\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3)-.001,\"mg/g\"\n", "print\"\\nAs the acid value is more than 0.1, oil cannot be used for lubrication\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.268 mg/g\n", "\n", "As the acid value is more than 0.1, oil cannot be used for lubrication\n", ] } ], "prompt_number": 2 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:3,Page no:28" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=20.#volume of oil saponified(ml)#\n", "den_oil=0.86#density f oil saponified(gm/ml)#\n", "volume=2.5#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.1#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.814 mg/g\n", ] } ], "prompt_number": 3 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:4,Page no:29" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=10.#volume of oil saponified(ml)#\n", "den_oil=0.92#density f oil saponified(gm/ml)#\n", "volume=4#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.01#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.243 mg/g\n", ] } ], "prompt_number": 4 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:5,Page no:27" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=9.#volume of oil saponified(ml)#\n", "den_oil=0.81#density f oil saponified(gm/ml)#\n", "volume=1.5#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.04#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.461 mg/g\n", ] } ], "prompt_number": 5 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:6,Page no:30" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=20.#volume of oil saponified(ml)#\n", "den_oil=0.86#density f oil saponified(gm/ml)#\n", "volume=2.8#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=1./10.#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3)-.001,\"mg/g\"\n", "print\"\\nAs the acid value is more than 0.1, oil cannot be used for lubrication\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.911 mg/g\n", "\n", "As the acid value is more than 0.1, oil cannot be used for lubrication\n", ] } ], "prompt_number": 6 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:7,Page no:30" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=7.#volume of oil saponified(ml)#\n", "den_oil=0.88#density f oil saponified(gm/ml)#\n", "volume=3.8#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.02#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,2),\"mg/g\"\n", "print\"\\nAs the acid value is more than 0.1, oil cannot be used for lubrication\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.69 mg/g\n", "\n", "As the acid value is more than 0.1, oil cannot be used for lubrication\n", ] } ], "prompt_number": 7 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:8,Page no:31" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=6.#volume of oil saponified(ml)#\n", "den_oil=0.91#density f oil saponified(gm/ml)#\n", "volume=2.6#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.02#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3),\"mg/g\"\n", "print\"\\nAs the acid value is more than 0.1, oil cannot be used for lubrication\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.533 mg/g\n", "\n", "As the acid value is more than 0.1, oil cannot be used for lubrication\n", ] } ], "prompt_number": 8 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:9,Page no:31" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=1.3#weight f oil saponified(gms)#\n", "volume=0.8#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=0.001#normality of KOH #\n", "\n", "#Calculation\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,5),\"mg/g\"\n", "print\"\\nAs the acid value is less than 0.1, oil can be used for lubrication\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.0.03446 mg/g\n", "\n", "As the acid value is less than 0.1, oil can be used for lubrication\n", ] } ], "prompt_number": 9 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:10,Page no:32" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "vol_oil=10.#volume of oil saponified(ml)#\n", "den_oil=0.91#density f oil saponified(gm/ml)#\n", "volume=5.#volume of alcoholic KOH consumed to neutralize fatty acids(ml)#\n", "normality_KOH=1./50#normality of KOH #\n", "\n", "#Calculation\n", "wt_oil=vol_oil*den_oil\n", "A=volume*normality_KOH*56./wt_oil#formula for acid value#\n", "\n", "#Result\n", "print\"\\nAcid value of oil is \",round(A,3),\"mg/g\"\n", "print\"\\nAs the acid value is more than 0.1, oil cannot be used for lubrication\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 0.615 mg/g\n", "\n", "As the acid value is more than 0.1, oil cannot be used for lubrication\n", ] } ], "prompt_number": 10 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:1,Page no:33" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=2.5#weight f oil saponified(gms)#\n", "blank=49.0#volume blank titration reading(ml)#\n", "back=26.4#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "normality_KOH=0.4#normality of KOH#\n", "S=volume*normality_KOH*56/wt_oil#formula for saponification value#\n", "\n", "#Result\n", "print\"\\nSaponification value of oil is \",round(S,3),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Saponification value of oil is 202.496 mg/g\n", ] } ], "prompt_number": 11 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:2,Page no:33" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=5.#weight f oil saponified(gms)#\n", "blank=44.0#volume blank titration reading(ml)#\n", "back=17.#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "normality_KOH=0.5#normality of KOH#\n", "S=volume*normality_KOH*56/wt_oil#formula for saponification value#\n", "\n", "#Result\n", "print\"\\nSaponification value of oil is \",round(S,1),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Saponification value of oil is 151.2 mg/g\n", ] } ], "prompt_number": 12 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:3,Page no:34" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n","S=180.#Saponification value of oil#\n", "wt_oil=1.#weight f oil saponified(gms)#\n", "blank=50.#volume blank titration reading(ml)#\n", "normality_KOH=0.4#normality of KOH #\n", "\n", "#Calculation\n", "volume=S*wt_oil/(normality_KOH*56)#formula for saponification value#\n", "back=blank-volume#volume of alcoholic KOH consumed(ml)#\n", "\n", "#Result\n", "print\"\\nQuantity of alcoholic KOH required per gram is \",round(back),\"ml\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Quantity of alcoholic KOH required per gram is 42.0 ml\n", ] } ], "prompt_number": 13 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:4,Page no:35" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=2.5#weight f oil saponified(gms)#\n", "blank=40.#volume blank titration reading(ml)#\n", "back=20.#volume back titration reading(ml)#\n", "normality_KOH=0.25#normality of KOH #\n", "normality_HCl=.5#normality of HCl#\n", "\n", "#Calculation\n", "e=normality_HCl/normality_KOH#for equivalence in titration #\n", "volume=(blank-back)*e#volume of alcoholic KOH consumed(ml)#\n", "S=volume*normality_KOH*56/wt_oil#formula for saponification value#\n", "\n", "#Result\n", "print\"\\nSaponification value of oil is \",round(S),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Saponification value of oil is 224.0 mg/g\n", ] } ], "prompt_number": 14 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:5,Page no:35" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "S_C=192.#Saponification value of castor oil#\n", "wt_oil=16.#weight f oil saponified(gms)#\n", "blank=45.#volume blank titration reading(ml)#\n", "back=31.5#volume back titration reading(ml)#\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "N_H=0.5#normality of HCl in titration#\n", "\n", "#Calculation\n", "V_H=blank#volume of HCl in titration(ml)#\n", "V_K=50.#volume of KOH in titration(ml)#\n", "N_K=N_H*V_H/V_K#normality of KOH for equivalence#\n", "S_blended=volume*N_K*56./wt_oil#formula for saponification value#\n", "pc_C=(S_blended/S_C)*100#blend percentage#\n", "\n", "#Result\n", "print\"\\nPercentage of castor oil in blend is \",round(pc_C,3),\"%\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Percentage of castor oil in blend is 11.074 %\n", ] } ], "prompt_number": 15 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:6,Page no:36" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=3.#weight f oil saponified(gms)#\n", "blank=36.0#volume blank titration reading(ml)#\n", "back=12.#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "normality_KOH=0.5#normality of KOH#\n", "S=volume*normality_KOH*56/wt_oil#formula for saponification value#\n", "\n", "#Result\n", "print\"\\nSaponification value of oil is \",round(S),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Saponification value of oil is 224.0 mg/g\n", ] } ], "prompt_number": 16 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:7,Page no:37" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=1.55#weight f oil saponified(gms)#\n", "blank=20.0#volume blank titration reading(ml)#\n", "back=15.#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "normality_KOH=0.5#normality of KOH#\n", "S=volume*normality_KOH*56/wt_oil#formula for saponification value#\n", "\n", "#Result\n", "print\"\\nSaponification value of oil is \",round(S,2),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Saponification value of oil is 90.32 mg/g\n", ] } ], "prompt_number": 17 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:8,Page no:37" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "wt_oil=1.25#weight f oil saponified(gms)#\n", "blank=50.0#volume blank titration reading(ml)#\n", "back=7.5#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "normality_KOH=0.1#normality of KOH#\n", "S=volume*normality_KOH*56/wt_oil#formula for saponification value#\n", "\n", "#Result\n", "print\"\\nSaponification value of oil is \",round(S,1),\"mg/g\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Saponification value of oil is 190.4 mg/g\n", ] } ], "prompt_number": 18 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:9,Page no:38" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "S_C=188.#Saponification value of castor oil#\n", "wt_oil=12.3#weight f oil saponified(gms)#\n", "blank=45.#volume blank titration reading(ml)#\n", "back=30.2#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "N=0.5#normality of KOH for equivalence#\n", "S_blended=volume*N*56./wt_oil#formula for saponification value#\n", "pc_C=(S_blended/S_C)*100\n", "\n", "#Result\n", "print\"\\nPercentage of castor oil in blend is \",round(pc_C,2),\"%\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Acid value of oil is 17.92 %\n", ] } ], "prompt_number": 19 }, { "cell_type": "heading", "level": 2, "metadata": {}, "source": [ "Example no:10,Page no:38" ] }, { "cell_type": "code", "collapsed": false, "input": [ "#Variable declaration\n", "S_C=191.#Saponification value of castor oil#\n", "wt_oil=2.5#weight f oil saponified(gms)#\n", "blank=40.#volume blank titration reading(ml)#\n", "back=24.#volume back titration reading(ml)#\n", "\n", "#Calculation\n", "volume=blank-back#volume of alcoholic KOH consumed(ml)#\n", "N=0.5#normality of KOH for equivalence#\n", "S_blended=volume*N*56./wt_oil#formula for saponification value#\n", "pc_C=(S_blended/S_C)*100\n", "\n", "#Result\n", "print\"\\nPercentage of castor oil in blend is \",round(pc_C,2),\"%\"\n", "\n" ], "language": "python", "metadata": {}, "outputs": [ { "output_type": "stream", "stream": "stdout", "text": [ "\n", "Percentage of castor oil in blend is 93.82 %\n", ] } ], "prompt_number": 20 }, ], "metadata": {} } ] }