From 92cca121f959c6616e3da431c1e2d23c4fa5e886 Mon Sep 17 00:00:00 2001 From: hardythe1 Date: Tue, 7 Apr 2015 15:58:05 +0530 Subject: added books --- Thermodynamics_for_Engineers/Chapter_15_2.ipynb | 158 ++++++++++++++++++++++++ 1 file changed, 158 insertions(+) create mode 100755 Thermodynamics_for_Engineers/Chapter_15_2.ipynb (limited to 'Thermodynamics_for_Engineers/Chapter_15_2.ipynb') diff --git a/Thermodynamics_for_Engineers/Chapter_15_2.ipynb b/Thermodynamics_for_Engineers/Chapter_15_2.ipynb new file mode 100755 index 00000000..25cf3bae --- /dev/null +++ b/Thermodynamics_for_Engineers/Chapter_15_2.ipynb @@ -0,0 +1,158 @@ +{ + "metadata": { + "name": "", + "signature": "sha256:d798b16416897dedbfd57aff5c233c1f7e9c52a7f0081b45c972d6ab47468c7c" + }, + "nbformat": 3, + "nbformat_minor": 0, + "worksheets": [ + { + "cells": [ + { + "cell_type": "heading", + "level": 1, + "metadata": {}, + "source": [ + "Chapter 15 - Thermodynamics of chemical reactions" + ] + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 1 - Pg 318" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "#calculate the amount of dissociation\n", + "#Initalization of variables\n", + "import math\n", + "import numpy\n", + "kp=math.pow(10,(1.45))\n", + "#calculations\n", + "s=[1-kp*kp , 0, -3, 2]\n", + "vec=numpy.roots(s)\n", + "X=numpy.real(vec[2])\n", + "xper=X*100\n", + "#results\n", + "print '%s %.1f %s' %(\"Amount of dissociaton =\",xper,\"percent\")\n", + "print '%s %.3f %s %.3f %s %.3f %s' %(\"\\n Of each original mole of CO2, there will be\",X,\"mole of CO \",X/2.,\" mol of Oxygen and\",(1-X),\"mol of CO2\")\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "Amount of dissociaton = 12.7 percent\n", + "\n", + " Of each original mole of CO2, there will be 0.127 mole of CO 0.063 mol of Oxygen and 0.873 mol of CO2\n" + ] + } + ], + "prompt_number": 1 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 2 - Pg 319" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "#calculate the max. temperature reached\n", + "#Initalization of variables\n", + "U=121200. #Btu/mol\n", + "Uco2=51635. #Btu/mol\n", + "Un2=27589. #Btu/mol\n", + "Uco22=57875. #Btu/mol\n", + "Un22=21036. #Btu/mol\n", + "T1=5000. #R\n", + "T2=5500. #R\n", + "#calculations\n", + "Ut1=Uco2+1.88*Un2\n", + "Ut2=Uco22 + 1.88*Un22\n", + "print '%s' %(\"By extrapolation,\")\n", + "Tx=5710 #R\n", + "#results\n", + "print '%s %d %s' %(\"Max. Temperature reached =\",Tx,\"R\")\n", + "print '%s' %(\"The calculation for Ut2 is wrong in textbook. Please use a calculator.\")\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "By extrapolation,\n", + "Max. Temperature reached = 5710 R\n", + "The calculation for Ut2 is wrong in textbook. Please use a calculator.\n" + ] + } + ], + "prompt_number": 2 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 3 - Pg 319" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "#calculate the max. obtainable temperature\n", + "#Initalization of variables\n", + "print '%s' %(\"By trial and error,\")\n", + "import math\n", + "X=0.201\n", + "X1=0.2\n", + "R=59.3 #universal gas constant\n", + "T=5000 #R\n", + "U=121200 #Btu/mol\n", + "Uco2=51635. #Btu/mol\n", + "Un2=27907. #Btu/mol\n", + "U3=29616. #Btu/mol\n", + "U4=27589. #Btu/mol\n", + "#calculations\n", + "kp1=R*(1-X1)/math.pow(X1,1.5) /math.pow(T,0.5)\n", + "kp2=R*(1-X)/math.pow(X,1.5) /math.pow(T,0.5)\n", + "q=(1-X)*Uco2 + X*Un2+ X/2 *U3 +1.88*U4 + X*U\n", + "print '%s' %(\"Interpolating between T=4500 R and T=5000 R, we get\")\n", + "T2=4907 #R\n", + "#results\n", + "print '%s %d %s' %(\"Max. obtainable temperature =\",T2,\" R\")\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "By trial and error,\n", + "Interpolating between T=4500 R and T=5000 R, we get\n", + "Max. obtainable temperature = 4907 R\n" + ] + } + ], + "prompt_number": 3 + } + ], + "metadata": {} + } + ] +} \ No newline at end of file -- cgit