From c7fe425ef3c5e8804f2f5de3d8fffedf5e2f1131 Mon Sep 17 00:00:00 2001
From: hardythe1
Date: Tue, 7 Apr 2015 15:58:05 +0530
Subject: added books

---
 Physical_Chemsitry/Chapter8.ipynb | 218 ++++++++++++++++++++++++++++++++++++++
 1 file changed, 218 insertions(+)
 create mode 100755 Physical_Chemsitry/Chapter8.ipynb

(limited to 'Physical_Chemsitry/Chapter8.ipynb')

diff --git a/Physical_Chemsitry/Chapter8.ipynb b/Physical_Chemsitry/Chapter8.ipynb
new file mode 100755
index 00000000..7ee5bb63
--- /dev/null
+++ b/Physical_Chemsitry/Chapter8.ipynb
@@ -0,0 +1,218 @@
+{
+ "metadata": {
+  "name": "",
+  "signature": "sha256:56268e206bf92e9d6c6eb22d6025708a41b67ffcb1bed3001f2340e19e39294f"
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+  {
+   "cells": [
+    {
+     "cell_type": "heading",
+     "level": 1,
+     "metadata": {},
+     "source": [
+      "Chapter 8 - First law of thermodynamics"
+     ]
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 1 - pg 211"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Joules required\n",
+      "#Initialization of variables\n",
+      "P=1.0132*10**6 #dynes/cm**2\n",
+      "A=100 #cm**2\n",
+      "z=10 #cm\n",
+      "#calculations\n",
+      "w=P*A*z*10**-7\n",
+      "#results\n",
+      "print '%s %.4e %s' %(\"Joules =\",w,\"J\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Joules = 1.0132e+02 J\n"
+       ]
+      }
+     ],
+     "prompt_number": 1
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 2 - pg 211"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Calories required\n",
+      "#Initialization of variables\n",
+      "P=1.0132*10**6 #dynes/cm**2\n",
+      "A=100 #cm**2\n",
+      "z=10 #cm\n",
+      "#calculations\n",
+      "w=P*A*z*10**-7\n",
+      "cal=w/4.184\n",
+      "#results\n",
+      "print '%s %.3f %s' %(\"Calories =\",cal,\"cal\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Calories = 24.216 cal\n"
+       ]
+      }
+     ],
+     "prompt_number": 4
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 3 - pg 217"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Heat of vaporization and the Change in energy\n",
+      "#Initialization of variables\n",
+      "T=373.2 #K\n",
+      "n=1. #mol\n",
+      "qp=9720. #cal/mol\n",
+      "#calculations\n",
+      "q=n*qp\n",
+      "w=1.987*T\n",
+      "dE=q-w\n",
+      "#results\n",
+      "print '%s %d %s' %(\"Heat of vaporization =\",q,\"cal\")\n",
+      "print '%s %d %s' %(\"\\n Change in energy =\",dE,\"cal\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Heat of vaporization = 9720 cal\n",
+        "\n",
+        " Change in energy = 8978 cal\n"
+       ]
+      }
+     ],
+     "prompt_number": 3
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 4 - pg 222"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the work done, Heat transferred and change in energy\n",
+      "#Initialization of variables\n",
+      "T1=25+273. #K\n",
+      "T2=25+273. #K\n",
+      "#calculations\n",
+      "print \"Since, T2=T1, dE=0\"\n",
+      "dE=0\n",
+      "w=0\n",
+      "q=dE+w\n",
+      "#results\n",
+      "print '%s %d %s' %(\"\\n Work done = \",w,\"J\")\n",
+      "print '%s %d %s' %(\"\\n Heat transferred =\",q,\"J\")\n",
+      "print '%s %d %s' %(\"\\n Change in energy = \",dE,\"J\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Since, T2=T1, dE=0\n",
+        "\n",
+        " Work done =  0 J\n",
+        "\n",
+        " Heat transferred = 0 J\n",
+        "\n",
+        " Change in energy =  0 J\n"
+       ]
+      }
+     ],
+     "prompt_number": 5
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 5 - pg 224"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Vibrational energy\n",
+      "#Initialization of variables\n",
+      "R=1.987 #cal/deg mol\n",
+      "#calculations\n",
+      "Cvtr=1.5*R\n",
+      "Cvrot=1.5*R\n",
+      "Cvt=Cvtr+Cvrot\n",
+      "print \"Observed Cv= 6.43\"\n",
+      "Cvobs=6.43\n",
+      "Cvvib=Cvobs-Cvt\n",
+      "#results\n",
+      "print '%s %.2f %s' %(\"Vibrational =\",Cvvib,\"cal/deg mol\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Observed Cv= 6.43\n",
+        "Vibrational = 0.47 cal/deg mol\n"
+       ]
+      }
+     ],
+     "prompt_number": 6
+    }
+   ],
+   "metadata": {}
+  }
+ ]
+}
\ No newline at end of file
-- 
cgit