From fba055ce5aa0955e22bac2413c33493b10ae6532 Mon Sep 17 00:00:00 2001 From: hardythe1 Date: Tue, 5 May 2015 14:21:39 +0530 Subject: add books --- Physical_Chemsitry/Chapter19.ipynb | 356 ------------------------------------- 1 file changed, 356 deletions(-) delete mode 100755 Physical_Chemsitry/Chapter19.ipynb (limited to 'Physical_Chemsitry/Chapter19.ipynb') diff --git a/Physical_Chemsitry/Chapter19.ipynb b/Physical_Chemsitry/Chapter19.ipynb deleted file mode 100755 index 5b2d735e..00000000 --- a/Physical_Chemsitry/Chapter19.ipynb +++ /dev/null @@ -1,356 +0,0 @@ -{ - "metadata": { - "name": "", - "signature": "sha256:f00e66b23ba11c1502ba60271f6e9b549183dbf77dfd61ae21a7394bb7c1f4ce" - }, - "nbformat": 3, - "nbformat_minor": 0, - "worksheets": [ - { - "cells": [ - { - "cell_type": "heading", - "level": 1, - "metadata": {}, - "source": [ - "Chapter 19 - Photochemistry" - ] - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 1 - pg 488" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Overall transmittance\n", - "#Initialization of variables\n", - "r1=0.727\n", - "r2=0.407\n", - "#calculations\n", - "r3=r1*r2\n", - "#results\n", - "print '%s %.3f' %(\"Overall transmittance = \",r3)\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Overall transmittance = 0.296\n" - ] - } - ], - "prompt_number": 1 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 2 - pg 488" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Extinction coefficient\n", - "import math\n", - "#Initialization of variables\n", - "r=0.450\n", - "c=0.02 #M\n", - "l=4 #cm\n", - "#calculations\n", - "e=-math.log10(r) /(c*l)\n", - "#results\n", - "print '%s %.2f %s' %(\"Extinction coefficient =\",e,\"litres mole^-1 cm^-1\")\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Extinction coefficient = 4.33 litres mole^-1 cm^-1\n" - ] - } - ], - "prompt_number": 2 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 3 - pg 488" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Transmittance of the solution\n", - "#Initialization of variables\n", - "import math\n", - "from math import log10\n", - "r1=0.850\n", - "r2=0.50\n", - "#calculations\n", - "Da=-log10(r1)\n", - "Db=-log10(r2)\n", - "D=Da+Db\n", - "r3=10**(-D)\n", - "#results\n", - "print '%s %.3f' %(\"Transmittance of solution =\",r3)\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Transmittance of solution = 0.425\n" - ] - } - ], - "prompt_number": 3 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 4 - pg 491" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Extinction coefficient\n", - "#Initialization of variables\n", - "c=0.000025 #M\n", - "l=2 #cm\n", - "D=0.417\n", - "#calculations\n", - "e=D/(c*l)\n", - "#result\n", - "print '%s %d %s' %(\"Extinction coefficient =\",e,\" liters mole^-1 cm^-1\")\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Extinction coefficient = 8340 liters mole^-1 cm^-1\n" - ] - } - ], - "prompt_number": 4 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 5 - pg 491" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Kc for dissociation\n", - "#Initialization of variables\n", - "c=0.5 #M\n", - "c1=0.000025 #M\n", - "D2=0.280\n", - "D1=0.417\n", - "#calculations\n", - "c2=D2*c1/(D1)\n", - "dC=c1-c2\n", - "SCN=c- 6*c2 -4*dC\n", - "K=dC*SCN**2 /c2\n", - "#results\n", - "print '%s %.2f %s' %(\"Kc for dissociation =\",K,\" M^2\")\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Kc for dissociation = 0.12 M^2\n" - ] - } - ], - "prompt_number": 5 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 6 - pg 492" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the value of m\n", - "#Initialization of variables\n", - "import math\n", - "from math import log\n", - "D2=0.249\n", - "D1=0.172\n", - "a2=0.00752\n", - "a1=0.00527\n", - "#calculations\n", - "m=(log(D2) -log(D1))/(log(a2) - log(a1))\n", - "#results\n", - "print '%s %.2f' %(\"m = \",m)\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "m = 1.04\n" - ] - } - ], - "prompt_number": 6 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 7 - pg 495" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Increase in optical density\n", - "#Initialization of variables\n", - "c=0.1 #M\n", - "V=100 #ml\n", - "v1=25 #ml\n", - "D=0.980\n", - "d1=0.090\n", - "d2=0.150\n", - "#calculations\n", - "a=v1*c/V\n", - "b=(V-v1)*c/V\n", - "Da=a*d1/c\n", - "Db=b*d2/c\n", - "Ddash=Da+Db\n", - "dD=D-Ddash\n", - "#results\n", - "print '%s %.3f' %(\"Increase in optical density =\",dD)\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Increase in optical density = 0.845\n" - ] - } - ], - "prompt_number": 8 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 8 - pg 496" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the value of lambda for the reaction to occur\n", - "#Initialization of variables\n", - "E=50000. #cal/mol\n", - "#calculations\n", - "lam=2.8593/E\n", - "#results\n", - "print '%s %d %s' %(\"For the reaction to occur lambda <\",lam*10**8,\"A\")\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "For the reaction to occur lambda < 5718 A\n" - ] - } - ], - "prompt_number": 9 - }, - { - "cell_type": "heading", - "level": 2, - "metadata": {}, - "source": [ - "Example 9 - pg 497" - ] - }, - { - "cell_type": "code", - "collapsed": false, - "input": [ - "#calculate the Amount of reactant disappeared\n", - "#Initialization of variables\n", - "lam=3000*10**-8 #cm\n", - "ield=0.420\n", - "Et=70000 #cal\n", - "#calculations\n", - "E=2.8593/lam\n", - "n=ield*Et/E\n", - "#results\n", - "print '%s %.3f %s' %(\"Amount of reactant disappeared =\",n,\" mol\")\n" - ], - "language": "python", - "metadata": {}, - "outputs": [ - { - "output_type": "stream", - "stream": "stdout", - "text": [ - "Amount of reactant disappeared = 0.308 mol\n" - ] - } - ], - "prompt_number": 10 - } - ], - "metadata": {} - } - ] -} \ No newline at end of file -- cgit