From c7fe425ef3c5e8804f2f5de3d8fffedf5e2f1131 Mon Sep 17 00:00:00 2001
From: hardythe1
Date: Tue, 7 Apr 2015 15:58:05 +0530
Subject: added books

---
 Physical_Chemsitry/Chapter17.ipynb | 183 +++++++++++++++++++++++++++++++++++++
 1 file changed, 183 insertions(+)
 create mode 100755 Physical_Chemsitry/Chapter17.ipynb

(limited to 'Physical_Chemsitry/Chapter17.ipynb')

diff --git a/Physical_Chemsitry/Chapter17.ipynb b/Physical_Chemsitry/Chapter17.ipynb
new file mode 100755
index 00000000..6e295125
--- /dev/null
+++ b/Physical_Chemsitry/Chapter17.ipynb
@@ -0,0 +1,183 @@
+{
+ "metadata": {
+  "name": "",
+  "signature": "sha256:4d58417f5757dcfb290ed1ee0e2191d724d6d044069d2c21c72e96a05505c726"
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+  {
+   "cells": [
+    {
+     "cell_type": "heading",
+     "level": 1,
+     "metadata": {},
+     "source": [
+      "Chapter 17 - Resolving Kinetic data"
+     ]
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 1 - pg 446"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Order of the reaction\n",
+      "#Initialization of variablesx1=5\n",
+      "import math\n",
+      "from math import log\n",
+      "x2=20.\n",
+      "x1=5.\n",
+      "n1=7.49\n",
+      "n2=5.14\n",
+      "#calculations\n",
+      "n=(log(n1)-log(n2))/(log(100-x1) - log(100-x2))\n",
+      "#results\n",
+      "print '%s %.2f' %(\"Order of the reaction  = \",n)\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Order of the reaction  =  2.19\n"
+       ]
+      }
+     ],
+     "prompt_number": 1
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 2 - pg 448"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Order of the reaction\n",
+      "#Initialization of variablesx1=5\n",
+      "import math\n",
+      "from math import log\n",
+      "p2=169.\n",
+      "p1=363.\n",
+      "t1=410.\n",
+      "t2=880.\n",
+      "#calculations\n",
+      "ndash=(log(t2) - log(t1))/(log(p1) - log(p2))\n",
+      "n=ndash+1\n",
+      "#results\n",
+      "print '%s %.2f' %(\"Order of the reaction  = \",n)\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Order of the reaction  =  2.00\n"
+       ]
+      }
+     ],
+     "prompt_number": 2
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 3 - pg 454"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Activation energy and Z\n",
+      "#Initialization of variables\n",
+      "import math\n",
+      "R=1.987 #cal/deg/mol\n",
+      "k1=4.45*10**-5\n",
+      "k2=2.52*10**-6\n",
+      "T1=283+273.2 #K\n",
+      "T2=356+273.2 #K\n",
+      "#calculations\n",
+      "Ea=2.303*R*1.7530 /(1/T1 - 1/T2)\n",
+      "logZ= math.log10(k1) +Ea/(2.303*R*T1)\n",
+      "Z=10**logZ\n",
+      "#results\n",
+      "print '%s %d %s' %(\"Activation energy =\",Ea,\"cal/mol\")\n",
+      "print '%s %.1e %s' %(\"\\n Z =\",Z,\"lt /mol sec\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Activation energy = 38456 cal/mol\n",
+        "\n",
+        " Z = 5.7e+10 lt /mol sec\n"
+       ]
+      }
+     ],
+     "prompt_number": 3
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 5 - pg 456"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the Equlibrium constant\n",
+      "#Initialization of variables\n",
+      "g1=0.661\n",
+      "g2=0.899\n",
+      "g3=0.405\n",
+      "g4=0.803\n",
+      "g5=0.946\n",
+      "g6=0.614\n",
+      "k=1.33\n",
+      "#calculations\n",
+      "k0=k*g3/(g1*g2)\n",
+      "k2=k0*g4*g5/g6\n",
+      "#results\n",
+      "print '%s %.2f %s' %(\"Equlibrium constant =\",k2,\"lt/mol min\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "Equlibrium constant = 1.12 lt/mol min\n"
+       ]
+      }
+     ],
+     "prompt_number": 4
+    }
+   ],
+   "metadata": {}
+  }
+ ]
+}
\ No newline at end of file
-- 
cgit