From 6279fa19ac6e2a4087df2e6fe985430ecc2c2d5d Mon Sep 17 00:00:00 2001
From: kinitrupti
Date: Fri, 12 May 2017 18:53:46 +0530
Subject: Removed duplicates

---
 .../Chapter14.ipynb                                | 216 +++++++++++++++++++++
 1 file changed, 216 insertions(+)
 create mode 100755 Concepts_of_Thermodynamics_by_Obert_Edward_F/Chapter14.ipynb

(limited to 'Concepts_of_Thermodynamics_by_Obert_Edward_F/Chapter14.ipynb')

diff --git a/Concepts_of_Thermodynamics_by_Obert_Edward_F/Chapter14.ipynb b/Concepts_of_Thermodynamics_by_Obert_Edward_F/Chapter14.ipynb
new file mode 100755
index 00000000..3c8834de
--- /dev/null
+++ b/Concepts_of_Thermodynamics_by_Obert_Edward_F/Chapter14.ipynb
@@ -0,0 +1,216 @@
+{
+ "metadata": {
+  "name": ""
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+  {
+   "cells": [
+    {
+     "cell_type": "heading",
+     "level": 1,
+     "metadata": {},
+     "source": [
+      "Chapter 14 - Equilibrium and the third law"
+     ]
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 1 - Pg 372"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the equlibrium constant\n",
+      "#Initialization of variables\n",
+      "import math\n",
+      "n1=0.95\n",
+      "n2=0.05\n",
+      "n3=0.025\n",
+      "P=147 #psia\n",
+      "pa=14.7 #psia\n",
+      "#calculations\n",
+      "n=n1+n2+n3\n",
+      "p1=n1/n *P/pa\n",
+      "p2=n2/n *P/pa\n",
+      "p3=n3/n *P/pa\n",
+      "Kp1= p1/(p2*math.pow(p3,0.5))\n",
+      "Kp2= p1*p1 /(p2*p2 *p3)\n",
+      "#results\n",
+      "print '%s %.1f' %(\"In case 1, Equilibrium constant = \",Kp1)\n",
+      "print '%s %.1f' %(\"\\n In case 2, Equilibrium constant =  \",Kp2)\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "In case 1, Equilibrium constant =  38.5\n",
+        "\n",
+        " In case 2, Equilibrium constant =   1480.1\n"
+       ]
+      }
+     ],
+     "prompt_number": 1
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 2 - Pg 373"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the degree of dissociation\n",
+      "#Initialization of variables\n",
+      "kp=5. \n",
+      "import numpy\n",
+      "from numpy import roots\n",
+      "#calculations\n",
+      "vec=numpy.roots([24,0, 3,-2])\n",
+      "x=vec[2]\n",
+      "vec2=numpy.roots([249,0,3,-2])\n",
+      "y=vec2[2]\n",
+      "#results\n",
+      "print '%s %.2f' %(\"\\n degree of dissociation = \",x)\n",
+      "print '%s %.2f' %(\"\\n If pressure =10 . degree of dissociation =\",y)"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "\n",
+        " degree of dissociation =  0.34\n",
+        "\n",
+        " If pressure =10 . degree of dissociation = 0.18\n"
+       ]
+      },
+      {
+       "output_type": "stream",
+       "stream": "stderr",
+       "text": [
+        "-c:12: ComplexWarning: Casting complex values to real discards the imaginary part\n",
+        "-c:13: ComplexWarning: Casting complex values to real discards the imaginary part\n"
+       ]
+      }
+     ],
+     "prompt_number": 2
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 3 - Pg 373"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the degree of dissociation\n",
+      "#Initialization of variables\n",
+      "k=5.\n",
+      "import numpy\n",
+      "from numpy import roots\n",
+      "#calculations\n",
+      "p=[k*k-1, k-5*k*k,7*k*k, -3*k*k]\n",
+      "vec=roots(p)\n",
+      "x=vec[2]\n",
+      "#results\n",
+      "print '%s %.2f' %(\"degree of dissociation = \",x)\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "degree of dissociation =  0.78\n"
+       ]
+      }
+     ],
+     "prompt_number": 4
+    },
+    {
+     "cell_type": "heading",
+     "level": 2,
+     "metadata": {},
+     "source": [
+      "Example 4 - Pg 395"
+     ]
+    },
+    {
+     "cell_type": "code",
+     "collapsed": false,
+     "input": [
+      "#calculate the work done in all the cases\n",
+      "import math\n",
+      "#Initialization of variables\n",
+      "T=77+460. #R\n",
+      "x1=0.21\n",
+      "x2=1-x1\n",
+      "G=-169557 #Btu/mole\n",
+      "n1=1\n",
+      "n2=3.76\n",
+      "R0=1.986\n",
+      "v=0.0885\n",
+      "pi=14.7\n",
+      "J=778.\n",
+      "#calculations\n",
+      "dg1=-n1*R0*T*math.log(x1)\n",
+      "dg2=-n2*R0*T*math.log(x2)\n",
+      "dg=dg1+dg2\n",
+      "dG=dg+G\n",
+      "W=-dG\n",
+      "W2=-G\n",
+      "p=0.0004 #atm\n",
+      "G1=-n1*R0*T*math.log(1./p)\n",
+      "W3= -(dg1+G+G1)\n",
+      "dgf=v*pi*144/J\n",
+      "#results\n",
+      "print '%s %d %s' %(\"In case 1,Work done =\",W,\"Btu/mole C\")\n",
+      "print '%s %d %s' %(\"\\n In case 2,Work done =\",W2,\"Btu/mole C\")\n",
+      "print '%s %d %s' %(\"\\n In case 3,Work done =\",W3,\"Btu/mole C\")\n",
+      "print '%s %.2f %s' %(\"\\n In case 4,Work done =\",dgf,\" Btu/mole C\")\n"
+     ],
+     "language": "python",
+     "metadata": {},
+     "outputs": [
+      {
+       "output_type": "stream",
+       "stream": "stdout",
+       "text": [
+        "In case 1,Work done = 166947 Btu/mole C\n",
+        "\n",
+        " In case 2,Work done = 169557 Btu/mole C\n",
+        "\n",
+        " In case 3,Work done = 176236 Btu/mole C\n",
+        "\n",
+        " In case 4,Work done = 0.24  Btu/mole C\n"
+       ]
+      }
+     ],
+     "prompt_number": 5
+    }
+   ],
+   "metadata": {}
+  }
+ ]
+}
\ No newline at end of file
-- 
cgit