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+{
+ "metadata": {
+ "name": "",
+ "signature": "sha256:e6be7abf8c97801180567f4f6cb83dc9e729f9c81204b1adfe4e1f54ff45dd36"
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+ {
+ "cells": [
+ {
+ "cell_type": "heading",
+ "level": 1,
+ "metadata": {},
+ "source": [
+ "Chapter 11: Molecular Structure"
+ ]
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 11.1, page no. 380"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "\n",
+ "import math\n",
+ "\n",
+ "#Variable Declaration\n",
+ "\n",
+ "f = 1.15 * 10 ** 11 # Frequency(Hz)\n",
+ "h = 1.055 * 10 ** -34 # Planck's constant(J.s)\n",
+ " \n",
+ "#Calculation\n",
+ "\n",
+ "w = 2 * math.pi * f\n",
+ "Icm = h / w\n",
+ "\n",
+ "#Results\n",
+ "\n",
+ "print \"(a) The moment of inertia is\",round(Icm/10 **-46 , 2),\"X 10^-46 kg.m^2.\"\n",
+ "\n",
+ "\n",
+ "\n",
+ "#Variable Declaration\n",
+ "\n",
+ "Ac = 12.0 #atomic mass of carbon (u)\n",
+ "Ao = 16.0 #atomic mass of oxygen (u)\n",
+ "u = 1.66 * 10 ** -27#(kg)\n",
+ "\n",
+ "#Calculation\n",
+ "\n",
+ "mu = Ac* Ao /(Ac+Ao)\n",
+ "R0 = math.sqrt(Icm/(mu*u))\n",
+ "\n",
+ "#Results\n",
+ "\n",
+ "print \"(b) The bond length of the molecule is\",round(R0/10**-9,3),\"nm.\""
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "(a) The moment of inertia is 1.46 X 10^-46 kg.m^2.\n",
+ "(b) The bond length of the molecule is 0.113 nm.\n"
+ ]
+ }
+ ],
+ "prompt_number": 2
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 11.2, page no. 383"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "\n",
+ "\n",
+ "import math\n",
+ "\n",
+ "#Variable Declaration\n",
+ "\n",
+ "f = 6.42 * 10 ** 13 #frequency(Hz)\n",
+ "mu = 1.14 * 10 ** -26 #(kg)\n",
+ " \n",
+ "#Calculation\n",
+ "\n",
+ "w = 2 * math.pi * f\n",
+ "K = mu * w**2\n",
+ "\n",
+ "#Results\n",
+ "\n",
+ "print \"(a) The force constant for this molecule is \",round(K/10**3,2),\"X 10^3 N/m.\"\n",
+ "\n",
+ "\n",
+ "\n",
+ "#Variable Declaration\n",
+ "\n",
+ "h = 1.055 * 10 ** -34 #Planck's constant (J.s)\n",
+ "\n",
+ "#Calculation\n",
+ "\n",
+ "A = (h/(mu * w)) ** 0.5\n",
+ "\n",
+ "#Results\n",
+ "\n",
+ "print \"(b) The Vibration amplitude is\",round(A/10**-9,5),\"nm.\""
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "(a) The force constant for this molecule is 1.85 X 10^3 N/m.\n",
+ "(b) The Vibration amplitude is 0.00479 nm.\n"
+ ]
+ }
+ ],
+ "prompt_number": 6
+ }
+ ],
+ "metadata": {}
+ }
+ ]
+} \ No newline at end of file