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+{
+ "metadata": {
+ "name": ""
+ },
+ "nbformat": 3,
+ "nbformat_minor": 0,
+ "worksheets": [
+ {
+ "cells": [
+ {
+ "cell_type": "heading",
+ "level": 1,
+ "metadata": {},
+ "source": [
+ "Chapter 16: Free Electron Theory"
+ ]
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.1, Page 16.14"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "t = 0 # temperature in K\n",
+ "E = 10 # Fermi energy of electron in eV\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "\n",
+ "#Calculations\n",
+ "E_ = E * 3 / 5\n",
+ "v = sqrt(2 * E_ * e / m)\n",
+ "\n",
+ "#Result\n",
+ "print \"\\nAverage energy of electron is %.f eV\\nSpeed of electron is %.2e m/sec\"%(E_,v)"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "\n",
+ "Average energy of electron is 6 eV\n",
+ "Speed of electron is 1.45e+06 m/sec\n"
+ ]
+ }
+ ],
+ "prompt_number": 1
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.2, Page 16.14"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "t = 0 # temperature in K\n",
+ "E = 7.9 # Fermi energy in eV\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "\n",
+ "#Calculations\n",
+ "E_ = E * 3 / 5\n",
+ "v = sqrt(2 * E_ * e / m)\n",
+ "\n",
+ "#Result\n",
+ "print \"Average energy of electron is %.2f eV\\nSpeed of electron is %.2e m/sec\"%(E_,v)"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Average energy of electron is 4.74 eV\n",
+ "Speed of electron is 1.29e+06 m/sec\n"
+ ]
+ }
+ ],
+ "prompt_number": 2
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.3, Page 16.15"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "n = 2.5e28 # no. of free electron in per meter cube\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "h = 6.62e-34 # Planck constant in J-sec\n",
+ "\n",
+ "#Calculations\n",
+ "E = (h**2 / (8 * pi**2 * m)) * (3 * pi**2 * n)**(2./3) * (1. / e)\n",
+ "v = (h / (2 * pi * m)) * (3 * pi**2 * n)**(1./3)\n",
+ "\n",
+ "#Results\n",
+ "print \"Fermi energy is %.2f eV\\nSpeed of electron is %.2e m/sec\"%(E,v)"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Fermi energy is 3.12 eV\n",
+ "Speed of electron is 1.05e+06 m/sec\n"
+ ]
+ }
+ ],
+ "prompt_number": 3
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.4, Page 16.15"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "d = 8940 # density of copper in kg/m^3\n",
+ "w = 63.55 # atomic weight of copper\n",
+ "t = 0 # temperature in K\n",
+ "N = 6.02e26 # Avogadro no. in per kg\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "h = 6.62e-34 # Planck constant in J-sec\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "\n",
+ "#Calculations\n",
+ "V = w / d\n",
+ "n = N / V \n",
+ "E = (h**2 / (8 * pi**2 * m)) * (3 * pi**2 * n)**(2./3) * (1. / e)\n",
+ "E_ = 3 * E / 5\n",
+ "\n",
+ "#Results\n",
+ "print \"Fermi energy is %.3f eV\\nAverage energy is %.2f eV\"%(E,E_)"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Fermi energy is 7.036 eV\n",
+ "Average energy is 4.22 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 4
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.5, Page 16.16\n"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "d = 10.5e6 # density of silver in g/m^3\n",
+ "w = 108 # atomic weight of silver\n",
+ "t = 0 # temperature in K\n",
+ "N = 6.02e23 # Avogadro no. in per kg\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "h = 6.62e-34 # Planck constant in J-sec\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "\n",
+ "#Calculations\n",
+ "V = w / d\n",
+ "n = N / V \n",
+ "E = (h**2 / (8 * pi**2 * m)) * (3 * pi**2 * n)**(2./3) * (1 / e)\n",
+ "\n",
+ "#Result\n",
+ "print \"Fermi energy is %.1f eV\"%E"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Fermi energy is 5.5 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 5
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.6, Page 16.16"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "a = 4e-10 # lattice constant in mr\n",
+ "t = 0 # temperature in K\n",
+ "N = 6.02e23 # Avogadro no. in per kg\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "h = 6.62e-34 # Planck constant in J-sec\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "\n",
+ "#Calculations\n",
+ "V = a**3\n",
+ "n = 4 / V \n",
+ "E = (h**2 / (8 * pi**2 * m)) * (3 * pi**2 * n)**(2./3) * (1 / e)\n",
+ "k = (3 * pi**2 *n)**(1./3)\n",
+ "KE = (3 * E / 5) * (n)\n",
+ "\n",
+ "#Results\n",
+ "print \"Fermi energy is %.2f eV\\nFermi vector is %.2e per m\\nTotal kinetic energy is %.2e eV\"%(E,k,KE)"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Fermi energy is 5.75 eV\n",
+ "Fermi vector is 1.23e+10 per m\n",
+ "Total kinetic energy is 2.15e+29 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 6
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.7, Page 16.17"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import pi\n",
+ "\n",
+ "# Given \n",
+ "d = 0.9e-3 # diameter of aluminium in m\n",
+ "i = 6 # current in amp\n",
+ "n = 4.5e28 # no. of electron available for conduction per meter^3 \n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "\n",
+ "#Calculations\n",
+ "J = i * 4 / (pi * (d)**2)\n",
+ "v = J / (n * e)\n",
+ "\n",
+ "#Result\n",
+ "print \"Drift velocity of electron is %.3e m/sec\"%v"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Drift velocity of electron is 1.310e-03 m/sec\n"
+ ]
+ }
+ ],
+ "prompt_number": 7
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.8, Page 16.17"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given \n",
+ "d = 8.92e3 # density of copper in kg/m^3\n",
+ "i = 5 # current in amp\n",
+ "w = 63.5 # atomic weight of copper\n",
+ "r = 0.7e-3 # radius in meter\n",
+ "N = 6.02e28 # Avogadro no.\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "\n",
+ "#Calculations\n",
+ "V = (w / d)\n",
+ "n = N / V \n",
+ "J = i / (pi * r**2)\n",
+ "v = J / (n * e)\n",
+ "\n",
+ "#Result\n",
+ "print \"Current density = %.2e amp/m^2\\nDrift velocity is %.1e m/sec\"%(J,v)\n",
+ "#Incorrect units in the textbook"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Current density = 3.25e+06 amp/m^2\n",
+ "Drift velocity is 2.4e-06 m/sec\n"
+ ]
+ }
+ ],
+ "prompt_number": 8
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.9, Page 16.17"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ "from math import *\n",
+ "\n",
+ "# Given\n",
+ "d1= 0.534*10**3 # densiy of Li in kg/m^3\n",
+ "d2= 0.971*10**3 # densiy of Na in kg/m^3\n",
+ "d3= 0.86*10**3 # densiy of K in kg/m^3\n",
+ "w1 = 6.939 # atomic weight of Li \n",
+ "w2 = 22.99 # atomic weight of Na\n",
+ "w3 = 39.202 # atomic weight of K\n",
+ "h = 6.62e-34 # Planck constant in J sec\n",
+ "m = 9.1e-31 # mass of an electron in kg\n",
+ "NA = 6.023e26 # Avogadro no.\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "\n",
+ "#Calculations\n",
+ "# For Li\n",
+ "n1 = NA * d1/w1\n",
+ "E1 = h**2/(8*pi**2*m)*(3*pi**2*n1)**(2./3)\n",
+ "# For Na\n",
+ "n2 = NA * d2/w2\n",
+ "E2 = h**2/(8*pi**2*m)*(3*pi**2*n2)**(2./3)\n",
+ "# For K\n",
+ "n3 = NA * d3/w3\n",
+ "E3 = h**2/(8*pi**2*m)*(3*pi**2*n3)**(2./3)\n",
+ "\n",
+ "#Results\n",
+ "print \"Fermi Energy \\nFor Li is %.2f eV\\nFor Na is %.3f eV \\nFor K is %.3f eV\"%(E1/e,E2/e,E3/e)\n"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Fermi Energy \n",
+ "For Li is 4.71 eV\n",
+ "For Na is 3.156 eV \n",
+ "For K is 2.039 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 9
+ },
+ {
+ "cell_type": "heading",
+ "level": 2,
+ "metadata": {},
+ "source": [
+ "Example 16.10, Page 16.18\n"
+ ]
+ },
+ {
+ "cell_type": "code",
+ "collapsed": false,
+ "input": [
+ " \n",
+ "# Given \n",
+ "l = 1e-10 #length of box in m\n",
+ "e = 1.6e-19 # charge on an electron in C\n",
+ "m = 9.1e-31 # mass of electron in kg\n",
+ "h = 6.62e-34 # Planck constant in J-sec\n",
+ "\n",
+ "#Calculations\n",
+ "n = 1 # for n=1\n",
+ "E = (n**2 * h**2) / (8 * m * l**2)\n",
+ "n = 2 # for n=2\n",
+ "E_ = (n**2 * h**2) / (8 * m * l**2)\n",
+ "d = (E_ - E) * (1 / e)\n",
+ "\n",
+ "#Result\n",
+ "print \"Energy difference is %.2f eV\"%d"
+ ],
+ "language": "python",
+ "metadata": {},
+ "outputs": [
+ {
+ "output_type": "stream",
+ "stream": "stdout",
+ "text": [
+ "Energy difference is 112.87 eV\n"
+ ]
+ }
+ ],
+ "prompt_number": 10
+ }
+ ],
+ "metadata": {}
+ }
+ ]
+} \ No newline at end of file