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author | nice | 2014-09-15 12:50:58 +0530 |
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committer | nice | 2014-09-15 12:50:58 +0530 |
commit | dfe3c858e90bb33c32f84a46e0a17cdd93b38e11 (patch) | |
tree | 8c68c3908ca451c3c8362fa104272af669de99d8 /Engineering_&_Chemical_Thermodynamics/ch7.ipynb | |
parent | cb9f5bedfa86923784f479aff86cd9d22c09f0ff (diff) | |
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diff --git a/Engineering_&_Chemical_Thermodynamics/ch7.ipynb b/Engineering_&_Chemical_Thermodynamics/ch7.ipynb new file mode 100755 index 00000000..16e8e4f7 --- /dev/null +++ b/Engineering_&_Chemical_Thermodynamics/ch7.ipynb @@ -0,0 +1,197 @@ +{ + "metadata": { + "name": "" + }, + "nbformat": 3, + "nbformat_minor": 0, + "worksheets": [ + { + "cells": [ + { + "cell_type": "heading", + "level": 1, + "metadata": {}, + "source": [ + "Chapter 7 : Phase Equilibia 2 Fugacity" + ] + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 7.1 Page No : 397" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "\n", + "import math \n", + "\n", + "# Variables\n", + "h_cap_H2O = 2676.0 ; \t\t\t#[kJ/kg],From steam table\n", + "S_cap_H2O = 7.3548 ; \t\t\t#[kJ/kgK],From steam table\n", + "h_cap_0_H2O = 2687.5 ; \t\t\t#[kJ/kg],From Appendix B\n", + "S_cap_0_H2O = 8.4479 ; \t\t\t#[kJ/kgK],From Appendix B\n", + "P_0_H2O = 10. ;\t\t\t#[kPa]\n", + "T = 373.15 ;\t\t\t#[K]\n", + "R = 8.314 / 18 ;\n", + "P_sys = 101.35 ;\t\t\t#[kPa]\n", + "\n", + "# Calculations\n", + "g_cap_H2O = h_cap_H2O - T * S_cap_H2O ;\n", + "g_cap_0_H2O = h_cap_0_H2O - T * S_cap_0_H2O ; \n", + "\n", + "f_H2O = P_0_H2O * math.exp((g_cap_H2O - g_cap_0_H2O ) / (R * T)) ;\n", + "\n", + "Sai_H2O = f_H2O / P_sys ;\n", + "\n", + "\n", + "# Results\n", + "print \"The fugacity = %.2f kPa The fugacity coefficient = %.3f\"%(f_H2O,Sai_H2O);\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "The fugacity = 99.73 kPa The fugacity coefficient = 0.984\n" + ] + } + ], + "prompt_number": 1 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 7.3 Page No : 402" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "# Variables\n", + "P = 50. \t\t\t#[bar]\n", + "T = 25. + 273.2\t\t\t#[K]\n", + "P_c = 48.7 ; \t\t\t#[bar] , From Appendix A.1 Table C.7 & C.8\n", + "T_c = 303.5 ; \t\t\t#[K] , From Appendix A.1 Table C.7 & C.8\n", + "w = 0.099 ; \t\t\t# From Appendix A.1 Table C.7 & C.8\n", + "log_w_0 = -0.216 ;\t\t\t# By interpolation\n", + "log_w_1 = -0.060 ;\t\t\t# By interpolation\n", + "\n", + "# Calculations\n", + "X = log_w_0 + w * log_w_1 ;\n", + "sai_eth = 10**(X) ;\n", + "f_eth = sai_eth * P ;\n", + "\n", + "# Results\n", + "print \"Fugacity = %.f bar\"%(f_eth);\n", + " \n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "Fugacity = 30 bar\n" + ] + } + ], + "prompt_number": 2 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 7.10 Page No : 435" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "# Variables\n", + "import math\n", + "gama_a_inf = 0.88 ;\n", + "gama_b_inf = 0.86 ;\n", + "R = 8.314 ;\n", + "T = 39.33 + 273 ;\n", + "\n", + "# Calculations\n", + "A_1 = R * T * math.log(gama_a_inf) ;\n", + "A_2 = R * T * math.log(gama_b_inf) ;\n", + "A = (A_1 + A_2) / 2 ;\n", + "\n", + "# Results\n", + "print \"The average value of two-suffix Margules parameter A = %.f J/mol\"%(A);\n" + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "The average value of two-suffix Margules parameter A = -362 J/mol\n" + ] + } + ], + "prompt_number": 4 + }, + { + "cell_type": "heading", + "level": 2, + "metadata": {}, + "source": [ + "Example 7.13 Page No : 448" + ] + }, + { + "cell_type": "code", + "collapsed": false, + "input": [ + "# Variables\n", + "A_T1 = 1401. ; \t\t\t#[J/mol]\n", + "T1 = 10 + 273. ;\t\t\t#[K]\n", + "T2 = 60 + 273. ; \t\t\t#[K]\n", + "C = 3250. ;\n", + "A_T2_prev = 1143. ;\t\t\t#[J/mol]\n", + "\n", + "# Calculations and Results\n", + "A_T2 = T2 * (C *(1./T2 - 1./T1) + A_T1 / T1);\n", + "print \"Value of A at 60*C = %.f J/mol\"%(A_T2) ;\n", + "\n", + "x = (A_T2_prev - A_T2) / A_T2_prev* 100 ;\n", + "print \"The values differ by = %.f %%\"%(x)\n", + "\n", + "# Note: Answer may vary because of rounding off error. " + ], + "language": "python", + "metadata": {}, + "outputs": [ + { + "output_type": "stream", + "stream": "stdout", + "text": [ + "Value of A at 60*C = 1074 J/mol\n", + "The values differ by = 6 %\n" + ] + } + ], + "prompt_number": 2 + } + ], + "metadata": {} + } + ] +}
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